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高能辐射对超高分子量聚乙烯纤维结构和力学性能的影响 被引量:2

EFFECT OF ELECTRON BEAM RADIATION ON THE STRUCTURE AND MECHANICAL PROPERTIES OF ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE FIBERS
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摘要 通过高能电子束对超高分子量聚乙烯纤维进行辐射交联,探讨了在不同辐照环境中辐射前后的结构和力学性能的变化。结果表明:凝胶含量和交联度随剂量的增加而增加,溶胀度和交联网链平均分子量随剂量的增加而降低,拉伸强度和断裂伸长率随剂量的增加而降低,拉伸模量随剂量的增加而增加。在空气、真空和乙炔气三种环境中辐照,以乙炔气环境中辐照效果最好,空气中最差。 Ultra high molecular weight polyethylene fibers have been crosslinked by electron beam. The structure and mechanical properties of them have been investigated in different irradiation atmospheres. The obtained results show that the gel content and crosslinking density increase with the increase of dose, the swelling ratio and average molecular weight of crosslinked net decrease with the increase of dose,the tensile strength and failure elongation decrease with the increase of dose, the tensile modulus increases with the increase of dose.When the samples are irradiated in air, vaccum and acetylene atmospheres,the effect of irradiation in acetylene atmosphere is best.
出处 《辐射研究与辐射工艺学报》 CAS CSCD 北大核心 1998年第3期135-140,共6页 Journal of Radiation Research and Radiation Processing
基金 "九五"国防重点预研项目
关键词 高能电子束 超高分子量 聚乙烯纤维 力学性能 Electron beam Irradiation crosslinking Ultra high molecular weight polyethylene fibers Structure Mechanical properties
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  • 1Manal Shaker. Effect of ionizing radiation on the properties of ultrahign molecular weight polycthylcnc fibers[J]. J Elastomers and Plastics, 1996,28(3) :236 - 256.
  • 2Toshio Ogawa, Hiroaki Mukai. improvement of the mechanical properties of an ultrahigh molecular weight polyethylene fiber/epoxy composites by corona-discharge treatment. Journal of Applied Polymer Science,2001,79(3) : 1 162
  • 3Masse P,Cavrot J P. Adhension improvement of high modulus polyethylene fibers by surface plasma treatment:evaluation by pull-out testing. Polymer Composites, 1994, 15 (2) : 247
  • 4吴越,骆玉祥,胡福增,吴叙勤.液态氧化法处理超高分子量聚乙烯纤维[J].功能高分子学报,1999,12(4):427-430. 被引量:30
  • 5骆玉祥,吴越,胡福增,吴叙勤,关淑英.超高分子量聚乙烯纤维紫外接枝处理[J].复合材料学报,2001,18(4):29-33. 被引量:22

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