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不同燃烧当量比对二甲醚燃烧的影响研究 被引量:1

EFFECT OF EQUIVALENCE RATIO ON THE COMBUSTION OF DIMETHYL ETHER/OXYGEN/ARGON FLAMES
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摘要 利用分子束质谱结合真空紫外同步辐射光电离技术研究了低压层流预混二甲醚/氧气/氩气火焰。通过测量火焰物种的离子信号强度随燃烧炉位置的关系曲线,计算了主要火焰物种的摩尔分数曲线。分析了燃料当量比(φ)为0.8,1.0和1.5时主要火焰物种的摩尔分数曲线,阐述了燃烧当量比对低压层流预混二甲醚/氧气/氩气火焰化学结构的影响。研究为进一步认识二甲醚燃烧提供了实验数据。 Dimethyl ether is regarded as a promising alternative fuel for engine, and much fundamental work still need to be done in order to effectively utilize it. In this paper, the experimental results of low pressure premixed laminar dimethyl ether/oxygen/argon (DME/O2/Ar) flames with different equivalence ratios (0.8, 1.0, and 1.5) using molecular beam mass spectrometry combined with synchrotron radiation photoionization technology are presented. By measuring the signal intensities relative to the distances from the burner surface, mole fraction profiles of the major intermediates are derived. Mole fraction profiles are analyzed and compared among these flames. Effect of equivalence ratio on the chemical structure of these flames is illustrated. The experimental data will enhance the understanding of dimethyl ether combustion.
出处 《工程热物理学报》 EI CAS CSCD 北大核心 2009年第8期1419-1422,共4页 Journal of Engineering Thermophysics
基金 国家自然科学基金项目(No.50521604 No.50636040)
关键词 二甲醚 低压层流 预混燃烧 dimethyl ether low-pressure laminar premixed flame
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参考文献10

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同被引文献9

  • 1罗马吉,黄震,陈志,吕兴才,李德刚.二甲醚均质压燃燃烧的详细化学动力学模拟研究[J].汽车工程,2004,26(6):642-647. 被引量:7
  • 2郎静,张煜盛.论DME燃烧与微量污染物生成机理研究[J].内燃机工程,2005,26(6):30-34. 被引量:19
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  • 5TAKAHASHI K, YAMAMOTO O, INOMATA T, et al. Shock-tube studies on the reactions of dimethyl ether with oxygen and hydrogen atoms [J]. Interna- tional Journal of Chemical Kinetics, 2007, 39 (2) : 97- 108.
  • 6Hidaka Y, SATO K, YAMANE M. High-tempera- ture pyrolysis of dimethyl ether in shock waves [J]. Combustion and Flame, 2000, 123(1/2): 1-22.
  • 7KONG S C. A study of natural gas/DME combustion in HCCI engines using CFD with detailed chemical ki- netics [J]. Fuel, 2007, 86(10/11): 1483-1489.
  • 8QI Fei, YANG Rui, YANG Bin, et al. Isomeric iden- tification of polyeyclic aromatic hydrocarbons formed in combustion with tunable vacuum ultraviolet photoioni- zation [J]. Review of Scientific Instruments, 2006, 77 (8) : 84-101.
  • 9ZHAO Z, CHAOS M, KAZAKOV A, et al. Thermal decomposition reaction and a comprehensive kinetic model of dimethyl ether [J]. International Journal of Chemical Kinetics, 2007, 40(1): 1-18.

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