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T700/氰酸酯/环氧树脂复合材料的“离位”增韧 被引量:3

Ex-Situ Toughening of T700/Cyanate Ester/Epoxy Resin Composites
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摘要 针对氰酸酯采用环氧树脂进行改性研究,对该体系的流变性能与DMA进行分析,并对浇注体的力学性能进行了研究。以聚砜作为增韧剂,采用"离位"增韧技术,制备复合材料层压板,测试了复合材料的力学性能与冲击后压缩强度(CAI),对微观增韧机理进行了研究。结果表明,在40℃时,氰酸酯/环氧树脂体系有较长的工艺适用期,很好的工艺操作性。Tg为200℃时,浇注体的力学性能优良。采用热塑性树脂作为"离位"增韧层,体系出现了相反转结构,具有较好的增韧效果,复合材料的CAI值从180MPa增加到260MPa,对复合材料的力学性能没有影响。 Cyanate ester/epoxy matrices were studied through rheological, DMA and mechanical properties tests. Composites were prepared with polysulfone through ex-situ toughening technique. Compression strength after impact (CAI) and mechancal properties were studied. Microstructural scanning electron microscope (SEM). As a result, when thermoplastic phase inversion structure appeared. CAI can be significantly improved toughening while mechanical properties are uninfluenced. toughening mechanism was studied through resin was used as ex-situ toughening layer, from 180 MPa to 260 MPa by using ex-situ
出处 《宇航材料工艺》 CAS CSCD 北大核心 2009年第4期58-61,共4页 Aerospace Materials & Technology
关键词 氰酸酯 “离位”增韧改性 冲击后压缩强度 Cyanate ester, Ex-situ toughening, Compression strength after impact
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  • 1李文峰,梁国正,王志强,轩立新,冯青平,陈淳.改进的酚-溴化氰法合成酚醛型氰酸酯及其表征[J].航空学报,2004,25(4):406-410. 被引量:9
  • 2孙法胜,李玉泉,辛浩波.氰酸酯改性环氧树脂的研究进展[J].化学推进剂与高分子材料,2004,2(4):29-31. 被引量:4
  • 3杨建业,强军锋,余竹焕.氰酸酯树脂改性的研究现状[J].化工新型材料,2005,33(4):13-15. 被引量:7
  • 4李文峰,梁国正,陈淳,王国建.酚醛型氰酸酯与双酚A型环氧共固化反应的FTIR研究[J].高分子学报,2006,16(6):804-809. 被引量:7
  • 5[1]Hamerton I. Chemistry and Technology of Cyanate Ester Resins [M]. Glasgow: Chapman and Hall, 1994.
  • 6[2]Fang T, Shimp D A. Polycyanate esters: Science and applications [J]. Prog Polym Sci, 1995, 20, 61-118.
  • 7[3]Hamerton I. In: Dyson R W, ed. Specialty Polymers (Second edition) [M]. Glasgow: Blackie Academic and Professional, 1998.
  • 8[4]Hamerton I, Hay J H. Recent technological developments in cyanate ester resins [J]. High Perform Polym, 1998, 10: 163-174.
  • 9[5]Hamerton I, Hay J H. Recent developments in the chemistry cyanate ester resins [J]. Polym Int, 1998, 47: 465-473.
  • 10[6]Bauer M, Tanzer W, Much H, et al. Reactions of polyfunctional cyanuric acid esters with polyfunctional glycidylether I: Identification [J]. Acta Polym, 1989, 40(5): 335-340.

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