N-亚水杨基甘氨酸Schiff碱与硫酸钕配合物的合成和表征

Synthesis and characterization of the complex of neodymium sulphate with N salicylidene glycine Schiff base

用硫酸钕与Ｎ亚水杨基甘氨酸Ｓｃｈｉｆ碱在水溶液中反应，合成了钕的Ｓｃｈｉｆ碱配合物Ｎｄ２（ＳａｌＧｌｙ）２ＳＯ４·２Ｈ２Ｏ（Ｓａｌ＝亚水杨基，Ｇｌｙ＝甘氨酸），并用元素分析、摩尔电导、红外光谱、电子光谱、荧光光谱和差热热重分析对其组成和性质进行了研究．

he new complex of neodymium sulphate with N salicydene glycine Shiff base has been synthesized in aqueous solution. It is concluded that its formula of the complex is Nd 2(SalGly) 2SO 4·2H 2O(Sal=salicylidene, Gly=glycine). The composition and properties of the complex has been studied by elemental analysis, molar conductance, infrared, electronic and fluorescence spectra, thermogravimetric and differential thermal analysis.