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新方法制备三氧化钼/聚苯胺插层复合物 被引量：1

Novel Method for Preparing MoO_3/Polyaniline Layered Composite
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摘要 提出一种制备三氧化钼/聚苯胺层状复合物的新方法,打破了传统制备方法对(Li/Na)xMoO3前驱体、离子引发剂以及水溶液环境的依赖.该方法使用烷基胺为插层剂在三氧化钼层间插入苯胺单体,然后在空气中热处理引发层间苯胺聚合形成三氧化钼/聚苯胺层状复合物.X射线衍射、扫描电子显微镜、差热分析及VSM磁性能测试结果表明,该复合物具有清晰层状形貌,层间聚苯胺以平行于层板形式存在,聚苯胺与三氧化钼在复合后磁性能发生明显变化. A novel method is proposed for preparing MoO3/polyaniline composite with layered structure. The composite was prepared first by inserting aniline into MoO3 lattice using dodeeylamine-intercalated MoO3 as precursor, followed by successful polymerization in air. The composite was characterized by powder XRD, SEM, and TGA-DSC. A possible arrangement of intercalated aniline in the gallery of MoO3 is proposed. Its magnetic property has been studied by VSM at room temperature.
作者 向怡弦 董晓雯 潘庆谊 程知萱 徐甲强
机构地区 上海大学理学院
出处 《上海大学学报（自然科学版）》 CAS CSCD 北大核心 2009年第4期417-420,425,共5页 Journal of Shanghai University:Natural Science Edition
关键词 三氧化钼 聚苯胺 插层 层状复合材料 磁性 molybdenum trioxide polyaniline intercalation layered material magnestism
分类号 O612.6 [理学—无机化学]
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参考文献20

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上海大学学报（自然科学版）
2009年 第4期

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