摘要
本文通过4,5-二(苯甲酰甲硫基)-1,3-二硫杂环戊烯-2-硫酮与乙二醇反应生成其缩酮,然后在亚磷酸三甲酯作用下偶联,最后水解,首次成功地制得了四(苯甲酰甲硫基)四硫富瓦烯(TBMT-TTF)。用循环伏安法和UV-Vis光谱研究了有关电化学性质。为制备含羰基四硫富瓦烯提供了一条可行途径。
The reaction of 4,5 - bis(benzoylmethylthio) - 1,3 - dithio - 2 - thione with glycol gave the ketal, followed by coupling with P(OMe)s,and hydrolysis to give tetra (benzoylmethylthio) -tetrathiafulvalene(TBMT - TTF) .The electrochemical properties of the compound have been studied by cyclic voltammetry and UV - Vis spectroscopy. The incorporating carbonyl TTF could be prepared by this method.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
1998年第4期320-323,共4页
Chinese Journal of Organic Chemistry
基金
陕西省自然科学基金
