摘要
The title ligand(A) was synthesized through condensation of 2-pyridine aldehydeand L-methyl cysteine hydrochloride. The isomers of (A) were separated by column chromatography. The in-situ prepared catalyst from (A) with [Rh(COD)CI]2 (COD:cyclooctadiene) has been used to catalyze the asymmetric hydrosilylation of acetophenone. The resultsshowed that only the configuration of C4, but not that of C2 affected the optical yield andconfiguration of the products.
The title ligand(A) was synthesized through condensation of 2-pyridine aldehydeand L-methyl cysteine hydrochloride. The isomers of (A) were separated by column chromatography. The in-situ prepared catalyst from (A) with [Rh(COD)CI]2 (COD:cyclooctadiene) has been used to catalyze the asymmetric hydrosilylation of acetophenone. The resultsshowed that only the configuration of C4, but not that of C2 affected the optical yield andconfiguration of the products.
出处
《应用化学》
CAS
CSCD
北大核心
1998年第4期89-91,共3页
Chinese Journal of Applied Chemistry
关键词
吡啶基
甲酯基噻唑烷
不对称硅氢化
催化剂
pyridyl-carbomethoxy-thiazolidine, ligand,asymmetric hydrosilylation
