聚丙烯成核剂成核效应及热稳定性研究

STUDIES ON THE THERMAL STABILITY OF THENUCLEATING EFFECT OF NUCLEATINGAGENTS IN POLYPROPYLENE

为表征在聚合物材料热加工成型过程中成核剂的成核效果的热稳定性，设计了用反复升降温ＤＳＣ实验，通过观察聚合物结晶温度和结晶热焓在反复升降温过程中的变化来考察成核剂的成核效率的稳定性．研究了碳酸钙、苯甲酸钠、对苯二甲酸和脂肪二元酸：庚二酸、辛二酸、壬二酸及其与碳酸钙组成的双组分成核剂对聚丙烯结晶成核效果的热稳定性．结果表明，高熔点物质碳酸钙、对苯二甲酸、苯甲酸钠的成核效果的热稳定性高，而脂肪二元酸的成核热稳定性低．庚二酸与碳酸钙组成的双组分成核剂的成核热稳定性高，但辛二酸、壬二酸与碳酸钙组成的双组分成核剂的成核热稳定性没有得到改善．这可能是由于庚二酸与碳酸钙之间存在某种相互作用，从而使成核效果得以稳定，而辛二酸、壬二酸与碳酸钙组成的双组分成核剂中，两个组分基本独立存在．

An experimental method was designed to characterize the thermal stability of nucleating effect of nucleating agents by repeated heating cooling DSC experiments.The DSC results showed that calcium carbonate,sodium benzoate and terephthalic acid were the nucleating agents of polypropylene with high thermal stability of the nucleating effect,while the thermal stability of nucleating effect of pimelic acid,suberic acid,azelaic acid,and the two component nucleating agents suberic acid/calcium carbonate and azelaic acid/calcium carbonate were poor.But the two component nucleator,pimelic acid/calcium carbonate exhibited good thermal stability,which infer that there are some interactions between pimelic acid and calcium carbonate.