期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

锂离子电池用Na-Mn-O材料的合成及应用

Synthesis and applications of Na-Mn-O materials for lithium ion batteries
下载PDF
导出
摘要 Na-Mn-O材料可作为离子交换法制备层状LiMnO2的前体,同时也可以直接作为锂离子电池的正极材料,被认为是锂二次电池研究中很有前景的新型材料。本文重点介绍了Na-Mn-O材料的晶体结构、制备方法,以及以该材料为前体,通过离子交换法合成的LixMnO2正极材料的结构与电化学性能。同时讨论了Na-Mn-O材料在锂二次电池、钠离子电池以及其它一些方面的应用,分析了Na-Mn-O材料作为未来锂二次电池正极材料的发展趋势。 The Na-Mn-O materials can be used as a precursor for the synthesis of layered lithium manganese oxides via an ion exchange procedure, or directly be used as the cathode material for lithium ion batteries, which is considered to be a new promising material for secondary lithium batteries. This paper focuses on the structure and preparation methods of the Na-Mn-O material, especially the structure and electrochemical properties of LixMnO2 synthesized by ion exchange method using NaxMnO2 as a precursor. Simultaneously, the application of Na-Mn-O material for the lithium ion batteries, sodium ion batteries and other aspect are also discussed. The development trend of Na-Mn-O as cathode materials for future secondary batteries is analyzed.
作者 杨顺毅 王先友 杨振华 陈权启 王国宝
机构地区 湘潭大学化学学院
出处 《化工进展》 EI CAS CSCD 北大核心 2009年第9期1553-1558,共6页 Chemical Industry and Engineering Progress
基金 国家自然科学基金(20871101) 湖南省教育厅重点项目(08A067)资助
关键词 Na-Mn-O材料 LixMnO2 正极材料 锂离子电池 sodium manganese oxides material lithium manganese oxides cathode material lithium ion battery
分类号 O646 [理学—物理化学]
  • 相关文献

参考文献42

  • 1Huang Z F, Meng X, Wang C Z, et al. First-principles calculations on the Tahn-Teller distortion in lagered LiMnO2[J]. J. Power Sources, 2006, 158(2): 1394-1400.
  • 2Huang Z F, Zhang H Z, Wang C Z, et al. First-principles investigation on extraction of lithium ion from monoclinic LiMnO2[J]. Solid State Sciences, 2009, 11(1): 271-274.
  • 3Hinuma Y, Meng Y S, Kang K, et al. Phase transitions in the LiNi0.5Mn0.5O2 system with temperature[J]. Chem. Mater., 2007, 19 (7): 1790-1800.
  • 4Kang K, Meng Y S, Breger J, et al. Electrodes with high power and high capacity for rechargeable lithium batteries[J]. Science, 2006,311: 977-980.
  • 5Suresh P, Shukla A K, Munichandraiah N. Characterization of Zn- and Fe-subsfituted LiMnO2 as cathode materials in Li-ion cells[J]. J. Power Sources, 2006, 161(2): 1307-1313.
  • 6Robertson A D, Armstrong A R, Bruce P G. Layered LixMn1-yCoyO2 intercalation electrodessinfluence of ion exchange on capacity and structure upon cycling[J]. Chem. Mater., 2001, 13(7): 2380-2386.
  • 7Armstrong A R, Paterson A J, Robertson A D, et al. Nonstoichiometric layered LixMnyO2 with a high capacity for lithium intercalation/deintercalation[J]. Chem. Mater., 2002, 14(2): 710-719.
  • 8Paterson A J, Armstrong A R, Bruce P G. Stoichiometric LiMnO2 with a layered structure charge-discharge capacity and the influence of grinding[J]. J. Electrochem. Soc., 2004, 151(10): A1552-A1558.
  • 9Park S H, Lee Y S, Sun Y K. Synthesis and electrochemical properties of sulfur doped-LixMnO2-ySy materials for lithium secondary batteries[J]. Electrochem. Commun., 2003, 5(2): 124-128.
  • 10Komaba S, Yoshii K, Ogata A, et al. Structural and electrochemical behaviors of metastable Li2/3[Ni1/3Mn2/3]O2 modified by metal element substitution[J]. Electrochim. Acta, 2009, 54 (8): 2353-2359.

二级参考文献18

  • 1魏楸桐,郭瑞松,李海龙,王凤华.溶胶凝胶——燃烧法合成La_(0.7)Sr_(0.3)MnO_3阴极材料及其性能[J].电源技术,2005,29(5):286-288. 被引量：4
  • 2陈立宝,贺跃辉,汤义武.采用固相配位法制备超细LiMn_2O_4正极材料[J].中南大学学报（自然科学版）,2005,36(3):390-395. 被引量：12
  • 3胡传跃,李新海,王志兴,罗文斌.材料对锂离子电池热稳定性的影响[J].中南大学学报（自然科学版）,2005,36(4):587-593. 被引量：11
  • 4Tarascon J M, Kinnon W R Mc, Coowar F B, et al. Synthesis conditions and oxygen stoichiometry effects on Li insertion into the spinel LiMn2O4[J]. J Electrochem Soc, 1994, 141(6): 1421-1431.
  • 5Amatucci G, Pasquier A, Blyr A, et al. The elevated temperature performance of the LiMn2O4/C system: failure and solutions[J]. Eleetrochim Acta, 1999, 45(1/2): 255-271.
  • 6Vittins G, West K. Lithium Intercalation into Layered LiMnO2[J]. J Electrochem Soc, 1997, 144(8): 2587-2592.
  • 7Parant J P, Olazcuaga R, Devalette M, et al. Sur quelques nouvelles phases de formule NaxMnO2 (x≤1)[J]. J Solid State Chem, 1971, 3(1): 1-11.
  • 8LeGoff P, Baffler N, Bach S, et al. Structural and electrochemical characteristics of a lamellar sodium manganese oxide synthesized via a sol-gel process[J]. Solid State Ionics, 1993, 61(4): 309-315.
  • 9Bach S, Pereira-Ramos J P, Willmann P. A sodium layered manganese oxides as 3V cathode materials for secondary lithium batteries[J]. Electrochim Acta, 2006, 52(2): 504-510.
  • 10Paulsen J M, Dahn J R. Studies of the layered manganese bronzes, Na2/3[Mn1-xMx]O2 with M=Co, Ni, Li, and Li2/3[Mn1-xMx]O2 prepared by ion-exchange[J]. Solid State Ionics, 1999, 126(1/2): 3-24.

共引文献14

化工进展
2009年 第9期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部