摘要
为了进一步提高有机硅涂层的抗原子氧剥蚀能力,采用经硅烷偶联剂处理的纳米ZnO微粒,在聚酰亚胺薄膜基材表面制备出纳米ZnO-有机硅复合涂层.通过原子氧地面模拟试验,研究了纳米ZnO-有机硅复合涂层的质量损失、表面形貌及化学成分的变化规律.结果表明:经表面处理的纳米ZnO微粒可以均匀分布在有机硅涂层中,有效消除有机硅树脂成膜过程中产生的微裂纹.经过原子氧辐照试验,没有保护涂层的聚酰亚胺基材的质量损失较大,而涂覆纳米ZnO-有机硅复合涂层具有良好的抗原子氧剥蚀性能,其质量损失和微观表面形貌变化很小,并且随着涂层中纳米ZnO含量的增加,其抗原子氧剥蚀的能力进一步增强.
To improve the anti-atomic oxygen properties of silicone coating, nano-ZnO modified by silane coupling reagent was filled in the silicone resin and nano-ZnO/silicone composite coating on polyimide film was obtained. Polyimide with and without nano-ZnO/silicone coating was exposed to atomic oxygen（AO） in a ground-based AO effect simulation facility. The modified nano-ZnO particles were uniformly distributed within the silicone coating so that micro-cracks occurred during film-forming of the silicone were eliminated effectively. The AO experiment results indicate that polyimide is significantly eroded which is characterized by substantial weight loss and change of surface morphologies ; nano-ZnO/silicone coatings exhibit excellent properties for anti-atomic oxygen effects with little variation in weight or morphology. The anti-oxygen properties of the coatings were improved along with the increase of nano-ZnO content.
出处
《北京航空航天大学学报》
EI
CAS
CSCD
北大核心
2009年第7期824-827,881,共5页
Journal of Beijing University of Aeronautics and Astronautics
基金
航天科技创新基金资助项目(CASC0505)
关键词
纳米ZNO
改性
有机硅
原子氧
nano-ZnO
modification
silicone
atomic oxygen
