摘要
用β-环糊精二间羧基苯磺酸酯同三氯化铁形成配合物,在N,N-二甲基甲酰胺介质中与过氧化氢构筑模拟酶,作为新型催化剂体系,将苯胺氧化生成硝基苯,其催化反应速率是FeCl3+H2O2的91倍,是配合物的63倍。
A mimic enzyme was constructed by hydrogen peroxide and a complex, which was prepared from βcyclodextrin, mcarbonyl benzenesulfonyl chlorid and iron trichloride, in N,Ndimethylformamid. Aniline can be oxidized to nitrobenzene by the enzyme 91 times as fast as by FeCl3+H2O2 and 63 times as fast as by the complex alone.
出处
《合成化学》
CAS
CSCD
1998年第2期211-214,共4页
Chinese Journal of Synthetic Chemistry
基金
湖北省自然科学基金