摘要
在无水无氧的条件下,利用希夫碱邻香草醛缩间甲氧基苯胺与MTO合成了MTO配合物,并采用红外光谱和核磁共振氢谱对其进行了表征.经红外光谱证实所合成的配合物分子中存在O…H—N,CH N,Re O;核磁共振氢谱证实存在Re—CH3,2Ar—OCH3,2×C6H4,CH N,O…H—N.说明合成的配合物是邻香草醛缩间甲氧基苯胺希夫碱C15H15NO3.CH3ReO3.
Under anaerobic conditions in the water,MTO complexes were synthesized using o-vanillin SchitI base reduction and inter-methoxy-aniline MTO, and characterized using infrared spectroscopy and nuclear magnetic resonance spectra of hydrogen. The infrared spectra showed the molecular ofO…H-N,CH=N,Re=O in the complexs; and NMR spectrum indicated the existence of hydrogen Re-CH3.2Ar-OCH3,2×C6H4,CHiN.O…H-N, confirming the synthesis of complexes between o-vanillin reduction methoxyaniline Schiff base C15H15NO3·CH3ReO3.
出处
《材料研究与应用》
CAS
2009年第3期192-195,共4页
Materials Research and Application
基金
国家自然科学基金项目(NSFC20671047)
