固液界面高分子吸附研究(Ⅱ)──高分子在界面的吸附

ASTUDY ON ADSORPTION OF POLYMER AT THE SOLID/LIQUID INTERFACE（Ⅱ）──ADSORPTION BEHAVIOR OF POLYMER

用本文（I）报建立的高分子吸附模型，计算了高分子在界面区的浓度分布、高分子吸附层的厚度、吸附量、不同构型的链段长度及其分布等微观结构，考察了体相高分子浓度、高分子──溶剂相互作用参数、吸附能参数、高分子链长等对高分子吸附行为的影响．

The adsorption models of polymer at the solid/liquid interfaces developed in the previous paper were used to calculate the microscopic structrues of the polymer adsorption layers including polymer concentration profile in the region of the interface,thickness of adsorption layer,adsorption amout,and distributions and average lengths of chain configurations of train,loop and tail configurations.The influence on adsoprtion behavior by bulk polymer concentration,interaction parameter between polymer and solvent,adsoprtion energy parameter and chain length was investigated.