一类新型二硫纶金属配合物的超导性和超导理论模型

Superconductivity and Superconducting Theory Mode of a Type New Metal Dithiolene Complexes

报道了1，3－二流－2－硫酮－4，5－二硫酵（1，3－dithiole－2－thione－4，5－dithiolate，简记dmit）金属配合物的超导性；借助与标题配合物结构相似的四硫富瓦烯－四氰基喹喏二甲烷（TTF·TCNQ）电荷转移型化合物的晶体导电模型，阐述了标题配合物超导性的本质特征，讨论了它们的超导性与其结构的关系．

The superconductivity of metal 1, 3 - dithiole - 2 - thione - 4, 5 -dithiolate complexes were reported. The titIe complexes and tetrathiafulvalene - tetracyanoquinodimethana (TTF. TCNQ ) were analogousto charge transfer compound. According to the crystal conductance mode of TTF. TCNQ, the superconductivitycharacteristic of title complexes were dissected. The relation between superconductivity and structure of complexes was investigated.