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使用无转子硫变仪研究丁苯橡胶的硫化动力学 被引量:1

Study on the Kinetics of Styrene-butadiene Rubber Vulcanization by Vulcameter
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摘要 用硫变仪测试丁苯橡胶(SBR)的硫化曲线。丁苯橡胶的硫化过程遵循一级动力学反应,可以用方程ln(MH-Mt)=B-kt来表示。计算不同硫化温度的反应速率常数。根据Arrhenius公式计算得出硫化反应活化能为88.112kJ/mol。 Vulcanization curves of Styrene - butadiene Rubber (SBR) was tested by vulcanmeter. It was found that Vulcanization of SBR followed first - order kinetics and it was one stage reaction. It could be expressed by ina kinetic equation In( MH -M1) = B -kt, and get the kinetics rate constant. The rate constant of the vulcanization with a rise in temperature was well satisfied with Arrherius equation, giving activation energy E = 88. 112kJ/mol.
出处 《广州化工》 CAS 2009年第6期109-110,共2页 GuangZhou Chemical Industry
关键词 丁苯橡胶 硫化 动力学 Styrene - butadiene Rubber Vulcanization Kinetics
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参考文献6

  • 1王贵恒.高分子材料成型加工原理[M].化学工业出版社,2004:224-229.
  • 2Coran A. Y. Vulcanization, VI. A Model and Treatment for Scorch Delay Kinetics. Rubber Chem Technol, 1964, 37: 689.
  • 3Coran A. Y. Vulcanization, IV, Effect of compounding variables on the Nature of Rubber Networks. Rubber Chem Technol, 1964, 37: 673.
  • 4Ping - yue Wang, Hong - Lian Qian, He - Ping Yu. Kinetics of Natural Rubber Vulcanization in the End Stage of Curing Period. J Appl Polym Sei, 2006,101 : 580.
  • 5Ding R. , Leonov A. I. , Coran A. Y. A Study of the Vulcanization of the Vulcanization Kinetics of an Aceelerated - Sulfur Compound. Rubber Chem Technol, 1996, 69: 81.
  • 6Ding R. , Leonov A. I. A Kinetic Model for ? Sulfur Accelerated Yulcanization of a Natural Rubber Compound. J Appl Polym Sci, 1996, 61 : 455.

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同被引文献7

  • 1约翰S.迪克.橡胶技术配合与性能测试[M].北京:化学工业出版社,2005:10-12.
  • 2Nagel W R. Peroxide-cured elastomers with improved metal adhesion: US, 5776294[P]. 1998-07-07.
  • 3Susanta Mitra, Afshin Ghanbari -Siahkali, Helle Kern Reh- meier,et al. Chemical degradation of crosslinked ethylene- propylene-diene rubber in an acidic environment: Effect of peroxide crosslinking in the presence of a coagent[J]. Poly- mer Degradation and Stability, 2006,91 (1) : 81-93.
  • 4Wreesmann C T J,Talma A G,Endstra W C. Peroxide vul-canized rubber composition: US, 5292815[P]. 1994-03-08.
  • 5Dikland H G, Ruardy T, Van der Does L, et al. New coa- gents in peroxide vulcanization of EPM[J]. Rubber Chemis- try and Technology, 1993,66(5) : 693-711.
  • 6郭建华,曾幸荣,罗权焜.助交联剂对过氧化物硫化EPDM/白炭黑胶料力学性能的影响[J].特种橡胶制品,2011,32(4):1-5. 被引量:3
  • 7王奎,廖建和,廖禄生,段志松,赵伟,杨耀华,陈永平.蛋白质对天然橡胶硫化动力学的影响[J].弹性体,2012,22(6):15-18. 被引量:17

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