N-(4-吗啉甲基)靛红-3-缩氨基硫脲及其Mn(Ⅱ)配合物的合成

Synthesis of N-morpholin-4-ylmethyl-isatin-3-thiosemicarbazone and Its Mn(Ⅱ) Complex

以靛红为原料经Mannich反应和缩合反应合成了N-(4-吗啉甲基)靛红-3-缩氨基硫脲(L);L与MnCl2作用得到配位化合物[MnLH2O]Cl2,其结构经1HNMR,IR,MS和元素分析表征。

N-morpholin-4-ylmethyl-isatin-3-thiosemicarbazone （L） was synthesized from isatin by the Mannich reaction followed by a condensation with thiosemicarbazone. L reacted with MnCl2 to obtain a Mn（ Ⅱ ） complex{ [-MnLH2O] Cl2 }. The structure was charaterized by 1H NMR, IR, MS and elemental analysis.