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具有非穿插α-Po拓扑的Gd-Cu异金属配聚物 [Gd2Cu3 (bpy)2(ip)6]·6H2O 被引量：2

A new 3-D Gd-Cu heterometallic polymer [Gd_2Cu_3(bpy)_2(ip)_6]·6H_2O
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摘要 水热合成了一个新颖的三维孔状Gd-Cu异金属配聚物[Gd2Cu3(bpy)2(ip)6]·6H2O(1)(bpy=2,2'-联吡啶,H2ip=间苯二酸),并对其结构进行了表征.该化合物属于三斜晶系,空间群为P1,具有非穿插α-Po拓扑结构及一维孔道,且六核链状水簇横跨在一维孔道中.此外,对该化合物的热稳定性及顺磁光谱进行了测试.
作者 贾向丽 周健 赵俊伟 李朝晖 郑寿添 杨国昱
机构地区 中国科学院福建物质结构研究所结构化学国家重点实验室 河南大学化学化工学院 福州大学化学化工学院
出处 《科学通报》 EI CAS CSCD 北大核心 2009年第17期2439-2443,共5页 Chinese Science Bulletin
基金 国家杰出青年科学基金(批准号:20725101) 国家重点基础研究发展计划(编号:2006CB932904) 福建省自然科学基金(编号:E0510030,2008F3120) 国家自然科学基金(批准号:50872133,20821061) 中国科学院知识创新工程青年人才领域前沿项目(编号:KJCX2.YW.H01)资助
关键词 水热合成 α-Po拓扑 异金属配聚物
分类号 O631.3 [理学—高分子化学]
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参考文献30

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同被引文献16

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科学通报
2009年 第17期

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