摘要
采用复合作用力，以Ｎ－ｔｅｒｔ－Ｂｕｔｏｘｙ－Ｃａｒｂｏｎｙｌ－Ｌ－Ｔｒｙｐｔｏｐｈａｎ（Ｎ－ｔ－Ｂｏｃ－Ｌ－Ｔｒｐ）为烙印分子，合成了一种对 Ｎ－ｔ－Ｂｏｃ－ＤＬ－Ｔｒｙｐｔｏｐｈａｎ具有良好手性拆分作用的高效液相色谱固定相，并初步研究了其拆分其机理。
Synthesis of molecularly imprinted polymers (MIPs) against N-t-Boc-L-Tryptophan using both acidic monomer (methacrylic acid) and basic monomer (2-vinylpyridine) were reported. N-t-Boc- DL-Tryptophan was successfully discriminated and the mechanism of emantiomeric recognition is discussed.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
1998年第10期1251-1253,共3页
Chinese Journal of Analytical Chemistry
基金
国家自然科学基金
关键词
分子烙印
手性固定相
氨基酸衍生物
HPCL
固定相
Molecule imprinting, high performance liquid chromatography, chiral staionary phase, amino acid derivatives
