摘要
One dimensional chain cobalt coordination polymer has been synthesized with malic acid and cobalt (Ⅱ) chloride anhydrous,and characterized by the element analysis,IR,TGA and single crystal X-ray diffraction structure analysis.The title complex crystallizes in monoclinic system with space group P21,a=0.575 61(9) nm,b= 0.905 86(14) nm,c=0.841 02(13) nm,β=105.350(2)°;V=0.422 88(11) nm3,Z=2,Dc=1.924 Mg.m-3,μ=2.044 mm-1,F(000)=250,and final R1=0.029 3,wR2=0.074 2.The crystal structure shows that the cobalt ion is coordinated with four oxygen atoms from two different malate molecules and two oxygen atoms from two water molecules respectively,forming a distorted octahedral coordination geometry.Two adjacent cobalt (Ⅱ) atoms are bridged by one malate groups in bis-monodentate mode,constructing a one dimensional chain structure along b axis,with the adjacent Co …Co distance being 0.530 9 nm.Moreover,the molecules are packed in three-dimensional supramolecular network though the intermolecular hydrogen bonds.CCDC: 704441.
One dimensional chain cobalt coordination polymer has been synthesized with malic acid and cobalt（Ⅱ） chloride anhydrous, and characterized by the element analysis, IR, TGA and single crystal X-ray diffraction structure analysis. The title complex crystallizes in monoclinic system with space group P21, a=0.575 61（9） nm, b=0.905 86（14） nm, c=0.841 02（13） nm, β=105.350（2）°; V=0.422 88（11） nm3, Z=2, Dc=1.924 Mg·m-3, μ=2.044 mm-1, F（000）=250, and final R1=0.029 3, wR2=0.074 2. The crystal structure shows that the cobalt ion is coordinated with four oxygen atoms from two different malate molecules and two oxygen atoms from two water molecules respectively, forming a distorted octahedral coordination geometry. Two adjacent cobalt（Ⅱ） atoms are bridged by one malate groups in bis-monodentate mode, constructing a one dimensional chain structure along b axis, with the adjacent Co…Co distance being 0.530 9 nm. Moreover, the molecules are packed in three-dimensional supramolecular network though the intermolecular hydrogen bonds. CCDC： 704441.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2009年第10期1877-1881,共5页
Chinese Journal of Inorganic Chemistry
