二甲基锡双2-羟基-1-萘甲醛对苯二甲酰腙配合物的合成及晶体结构(英文)

Syntheses and Crystal Structure of Dimethyltin(Ⅳ) Complex with Bis(2-hydroxy-1-naphthaldehyde) 1,4-benzenedicarboxylic Acid Hydrazone

利用二甲基二氯化锡与双2-羟基-1-萘甲醛对苯二甲酰腙反应,合成了二甲基锡双2-羟基-1-萘甲醛对苯二甲酰腙配合物,并用元素分析、红外光谱、核磁共振谱和X-射线单晶衍射对该化合物进行了表征.

A new dimethyltin （IV） complex with bis （2-hydroxy-1-naphthaldehyde） terephthalo-hydrazone has been obtained by reaction of bis（2-hydroxy-l-naphthaldehyde） 1,4-benzenedicarboxylic acid hydrazone with dimethyltin（IV） dichloride in the presence of sodium ethoxide. The complex was characterized by elemental, IR,NMR and X-ray crystallography diffraction analyses.