摘要
由支持硅石的钠氢硫酸盐的本甲基酉旨的新 debenzylation 被描述。debenzylation 能有选择地并且高效地被完成在对没有影响象 nitro,不饱和的契约,和乙醇酉旨那样的敏感的功能的组的优秀收益好。
A new debenzylation of benzyl esters by silica-supported sodium hydrogen sulfate is described. The debenzylation could be achieved selectively and efficiently in good to excellent yields without affecting sensitive functional groups such as nitro, unsaturated bonds, and ethyl ester.
基金
support from National Science Foundation of China(Nos.03772648 and 30721005)
Knowledge Innovation Program of the Chinese Academy of Sciences(No.06G8031014)
关键词
硫酸氢钠
二氧化硅
苄酯
有效率
不饱和
硝基
乙酯
Debenzylation
Benzyl esters
Silica-supported sodium hydrogen sulphate