金属氢化物的反应活性与硬软酸碱原理

The Reactivity of the Metal Hydrides Reductions and HSAB Principle

本文利用羰基氧原子的电荷数与其半径之比分析了羧酸及其衍生物的碱的硬软度,并利用硬软酸碱原理解释了金属氢化物还原各种羧酸衍生物的活性差异.

This paper analyzes hardness or softness of Carboxylic acid and derivatives as Lewis bases using the ratio of the charge number to the radius of oxygen atom in carbonyl group.This paper also explaines the differance in activity of matal hydrides in reductions of the cerbonxylic acid and derivatives by HSAB principle.