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8-羟基喹啉-5-磺酸构筑的有机-无机配位化合物的合成、结构和性质研究

Synthesis,crystal structure and properties of inorganic-organic hybridpolymers based on 8-hydroxylquinoline-5-sulfonic acid
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摘要 在溶剂热条件下,以8-羟基喹啉-5-磺酸为配体,合成了两个新的有机-无机配位化合物Mn(QS)(H2O)(1)和Co(QS)(H2O)2(2)(H2QS=8-hydroxylquinoline-5-sulfonic acid),并且对他们进行了单晶X-射线解析.其中化合物1是一个具有金红石拓扑的三维开放骨架结构,化合物2是一个三维超分子结构.我们对这些化合物进行了粉末X射线,红外光谱,差热热重,荧光光谱和磁学性质的研究. Two new inorganic-organic hybrid polymers, Mn（QS）（H2O） （1） and Co（QS）（H2O）2 （2） （H2QS=8-hydroxylquinoline-5-sulfonic acid）, based on 8-hydroxylquinoline-5-sulfonate ligand, have been synthesized under solvothermal conditions and their structures were solved by single-crystal X-ray diffraction analysis. Compound 1 is a three-dimensional open framework with rutile topology structure, and compound 2 is a three-dimensional supramolecular structure. These compounds were characterized by powder XRD, infrared spectroscopy, thermogravimetric analysis, fluorescence properties and magnetism properties.
作者 王瑛 薛铭 徐家宁 朱广山 裘式纶
机构地区 吉林大学无机合成与制备国家重点实验室
出处 《中国科学（B辑）》 EI CSCD 北大核心 2009年第10期1159-1166,共8页 Science in China(Series B)
基金 国家重点基础研究发展计划(编号:2006CB806100) 国家自然科学基金杰出青年基金(批准号:20625102) 国家自然科学基金(批准号:20831D02 20571030 20531030 20371020)资助
关键词 有机-无机杂化材料 8-羟基喹啉-5-磺酸 荧光 磁性 Inorganic-organic hybrid polymers, 8-hydroxylquinoline-5-sulfonate, Fluorescence properties, Magnetism properties
分类号 O641.4 [理学—物理化学]
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参考文献29

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中国科学（B辑）
2009年 第10期

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