HMX与DMF的络合行为

The Complex Behavior of HMX and DMF

用傅立叶红外光谱(FTIR)、核磁共振(1H NMR)、X射线衍射光谱(XRD)研究了奥克托今(HMX)与二甲基甲酰胺(DMF)的络合行为。结果表明,HMX与DMF形成1:1的络合物(HMX(DMF)),络合发生在DMF的羰基与HMX的—CH2基团间,形成了与HMX晶型不同的新物相。

The complex behavior of HMX and DMF was studied by FTIR, ^1H NMR and XRD methods. Results show that the complex HMX（DMF） is formed in which molecule ratio of HMX and DMF is 1 ： 1 . Complex behavior occurs in the carbonyl of DMF and the --CH2 groups of HMX. The crystal of the complex is different from that of HMX and the complex is a new material phase.