一种含三嗪单元多齿手性配体的合成

Synthesis of a Chiral Ligand Containing 1,3,5-Triazine Unit

以(R,R)-1,2-二苯基乙二醇和氰尿酰氯为原料,经保护、醚化、去保护、取代等反应合成了一种新的手性多齿配体2-乙氧基-4-(2-甲氧基-乙氧基)-6-((1R,2R)-1,2-二苯基-2-甲氧基-乙氧基)-1,3,5-三嗪,并通过1H NMR、LCMS和元素分析测试技术对目标化合物的结构进行了表征。

A novel chiral polydentate ligand,2-ethoxy-4-（2-methoxy-ethoxy）-6-（（1R,2R）-1,2-diphenyl-2-methoxy-ethoxy）-1,3,5-triazine,was synthesized from（R,R）-hydrobenzoin and cyanuric chloride by means of functional group pretection,etherification,deprotection and substitution.The structure of the target product was characterized by ^1H NMR,LCMS and elemental analysis.