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(1-x)PMN-xPT铁电致冷陶瓷的研究 被引量:3

INVESTIGATION OF (1-x)PMN xPT FERROELECTRIC REFRIGERATION CERAMICS
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摘要 概括介绍了铁电致冷基本原理,给出了三种电生热效应,即线性电生热效应、二次电生热效应和电场诱导一级相变型电生热效应的表达式,测量了(1-x)Pb(Mg1/3Nb2/3)O3xPbTiO3[简记为(1-x)PMNxPT],当x=008,010和025时在室温附近的电生热性能,分析了其电生热效应的起源.研究结果表明,(1-x)PMNxPT铁电固溶体陶瓷在室温附近具有较大的电生热效应;该效应起源于电场诱导一级相变型电生热效应和线性电生热效应; AbstractIn recent years, the electrocaloric effect (abbr. ECE) of dielectrics has attracted attention for ferroelectric refrigerating application. The fundamentals of ferroelectric refrigeration and the expressions of three types of ECEs, i.e., linear, quadratic and fieldinduced firstorder phase transition electrocaloric effects, are presented in this paper. The ECE properties of (1-x)PbMg1/3Nb2/3O_3 xPbTiO_3[abbr. (1-x)PMN xPT] ferroelectric ceramics(x=0.08, 0.10, and 0.25 respectively) at room temperature were measured and analyzed. It is found that the large electrocaloric effect of (1-x)PMN xPT ferroelectric ceramics about room temperature is due to the electric induced first order phase transition and linear electrocaloric effects, and these ceramics could be used in ferroelectric multi stage refrigeration.
出处 《物理学报》 SCIE EI CAS CSCD 北大核心 1998年第10期1754-1760,共7页 Acta Physica Sinica
基金 国家自然科学基金
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参考文献11

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同被引文献11

  • 1肖定全,朱建国,杨斌,钱正洪,张文,杜晓松.铁电致冷材料及其应用[J].压电与声光,1994,16(5):31-35. 被引量:5
  • 2沈能钰 孙同年 余声明 等.现代电子材料技术-信息装备的基石[M].北京:国防工业出版社,2000..
  • 3[3]Zhang R,Peng S,Xiao D, et al. Preparation and Characterization of (1 - x) Pb (Mg1/3 Nb2/3 ) O3 -xPbTiO3 Electrocaloric Ceramics. Cryst. Res.Tech. ,1998,33(5): 827~832
  • 4沈能钰 孙同年 余声明.现代电子材料技术——信息装备的基石[M].北京:国防工业出版社,2000..
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  • 7ZHANG R, PENG S, XIAO D, et al. Preparation and characterization of (1-x) Pb (Mgx/3 Nb,/3 ) O3-x PbTiO3 electrocaloric ceramics [J]. Cryst Res Technol,1998, 33(5): 827-832.
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  • 9SHEBANNOV L, BORMANIS K, KALVANCE A.Recent trends in design electrcaloric active Ierroelectric ceramics [J]. Integrated Ferroelectrics, 2001,10:1 297-1 301.
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