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苯乙烯-甲基丙烯酸超浓乳液的制备及聚合 被引量:5

Preparation and Polymerization of Super Concentrated Emulsion of Styrene(St) Methacrylic Acid(MAA)
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摘要 超浓乳液聚合有着良好的应用前景[1,2].但文献报道的超浓乳液研究多集中于苯乙烯体系,而对于在此基础上引入功能基单体制备超浓乳液,研究得较少[3].本文研究了影响苯乙烯(St)与甲基丙烯酸(MAA)制备(St-MAA)超浓乳液稳定性的因素.探讨了其聚... The preparation of concentrated St MAA emulsion by one step method is investigated. The stability of the emulsion is affected by the kinds and concentration of the emulsifiers, volume fraction and polarity of the monomer. The polymerization of concentrated St MAA emulsion was carried out using azo bis isobutyronitrile as initiator. Results indicate that the average size and dispersity of the latex particles depend on the concentration of the surfacant and monomer fraction.
出处 《应用化学》 CAS CSCD 北大核心 1998年第5期53-55,共3页 Chinese Journal of Applied Chemistry
关键词 苯乙烯 甲基丙烯酸 超浓乳液 乳液聚合 芳聚 styrene,methylacrylic acid,concentrated emulsion,stability,emulsion polyme rization
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同被引文献42

  • 1张洪涛,李建宗.超浓乳液聚合及应用[J].高分子通报,1995(2):99-103. 被引量:8
  • 2Lissant K J, Mayhan K G. J Coll Interf[J]. Sci, 1973,42(1) :201.
  • 3Ruckenstein. E, Kim . K. J. Polymerization in gel-like emulsions[J]. J. Appl. Polym. Sci, 1988,36:907.
  • 4Ruckenstein . E, et al. Polymerization in gel-like emulsions[J]. J. Appl. Polym. Sci, 1988, 36: 907; 1992,46:1271.
  • 5Ruckenstein E,Li H Q. Polymer Bulletin 1996,37:43.
  • 6Zhang HongTao, Chen Min, Lv Rui. Journal of Applied Polymer Science. 2004, 91:570.
  • 7Zhang HongTao, Huang He, Cao Jianhua. Journal of Applied Polymer Science, 2004, 94:1.
  • 8Ruckenstein E, Kim K. J. Effect of electrolyte on concentrated emulsion[J]. J. appl. polym Sci, 1988, 36:907.
  • 9Ruckenstein E, Sun F. A new concentrated emulsion polymerization pathway[J]. J. Appl Polym. Sci, 1992,46:1271.
  • 10Ruckenstein E,Kim K.J. Polymerization in gel-like emulsions[J]. J. Appl. Polym. Sci, 1988,36:907.

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