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Preparation and properties of K_2NiF_4-type perovskite oxides La_2NiO_4 catalysts for steam reforming of ethanol 被引量:1

Preparation and properties of K_2NiF_4-type perovskite oxides La_2NiO_4 catalysts for steam reforming of ethanol
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摘要 The performance of La2NiO4 perovskite catalysts,prepared using a citric acid complexation method,for the steam reforming of ethanol was studied.The catalysts were characterized by X-ray diffractometry(XRD),specific surface area measurements(BET),thermogravimetric analysis(TGA)and scanning electron microscopy(SEM).The experimental results show that the calcination temperature and the amount of citric acid(CA)have a significant influence on the characteristics of the catalysts and their catalytic activity.Among the catalysts tested,the La2NiO4 catalyst calcined at 700 ℃withn(La):n(Ni):n(CA)of 2:1:3 exhibits the best activity and excellent stability as well as very low coke formation. The performance of La2NiO4 perovskite catalysts, prepared using a citric acid complexation method, for the steam reforming of ethanol was studied. The catalysts were characterized by X-ray diffractometry (XRD), specific surface area measurements (BET), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The experimental results show that the calcination temperature and thc amount of citric acid (CA) have a significant influence on the characteristics of the catalysts and their catalytic activity. Among the catalysts tested, the La2NiO4 catalyst calcined at 700 ℃ with n(La):n(Ni):n(CA) of 2:1:3 exhibits the best activity and excellent stability as well as very low coke formation.
出处 《中国有色金属学会会刊:英文版》 EI CSCD 2009年第6期1444-1449,共6页 Transactions of Nonferrous Metals Society of China
关键词 La2NiO4 重整催化剂 K2NiF4型 钙钛矿氧化物 乙醇 性能 扫描电子显微镜 蒸汽 hydrogen ethanol perovskite-like oxides La2NiO4
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