摘要
An unusual 3D porous network assembled by tridentate ligand Tbmiz [1,3,5- tris（benzimidazol-1-ylmethyl）-2,4,6-trimethylbenzene] and Cu-I cluster was synthesized by means of hydrothermal process. It crystallizes in the trigonal system, space group P-3c1 with a = 14.2362（8）, b = 14.2362（8）, c = 36.4017（35）A, γ = 120.00°, V = 6389.1（8）, Dc = 1.976 g/cm^3, Z = 2, μ（MoKα） = 0.71073 and F（000） = 3692.0. Of the 40832 total reflections, 3948 were unique （Rint = 0.0366）. The final R = 0.0460 and wR = 0.1335 for 3948 observed reflections with I 〉 2σ（I）.
An unusual 3D porous network assembled by tridentate ligand Tbmiz [1,3,5- tris（benzimidazol-1-ylmethyl）-2,4,6-trimethylbenzene] and Cu-I cluster was synthesized by means of hydrothermal process. It crystallizes in the trigonal system, space group P-3c1 with a = 14.2362（8）, b = 14.2362（8）, c = 36.4017（35）A, γ = 120.00°, V = 6389.1（8）, Dc = 1.976 g/cm^3, Z = 2, μ（MoKα） = 0.71073 and F（000） = 3692.0. Of the 40832 total reflections, 3948 were unique （Rint = 0.0366）. The final R = 0.0460 and wR = 0.1335 for 3948 observed reflections with I 〉 2σ（I）.
基金
Supported by the Young Talent Program of Fujian Province (No. 2007F3117)
Natural Science Foundation of Fujian Province (No. 2007J0001)
