期刊文献+

瓦斯传感器MnO_2/Al_2O_3催化材料的研制

Study on MnO_2/Al_2O_3 Sensitive Materials for CH_4 Gas
下载PDF
导出
摘要 采用室温固相合成法制备了不同含量的MnO_2/Al_2O_3系列敏感材料,试验研究了MnO_2催化剂含量和焙烧温度对甲烷气体催化活性的影响,并考察了甲烷传感器灵敏度大小及敏感材料的长期稳定性。结果表明:该法制备的MnO_2/Al_2O_3系列敏感材料具有较好的低温催化活性,且随MnO_2含量的增加,催化剂的低温活性增强。综合考虑敏感材料的催化活性、灵敏度和稳定性,400℃焙烧制备的MnO_2含量为30%的MnO_2/Al_2O_3敏感材料对甲烷低温催化燃烧有较好的催化性能。 A series of MnO2/Al2O3 sensitive materials were prepared via solid-state reaction. The Influence of MnO2 catalytic contents and baked temperature on catalytic performance were studied. In addition, the size of sensitivity and the long-term stability of sensitive materials were investigated. The results show that the sensitive materials with higher MnO2 contents have higher catalytic activity in low temperature. Considering catalytic activity, sensitivity and the long-term stability of sensitive materials, the 30% MnO2/Al2O3 baked at 400 ℃is found to be the best sensitive materials for methane low temperature catalytic reaction.
出处 《仪表技术与传感器》 CSCD 北大核心 2009年第B11期107-109,152,共4页 Instrument Technique and Sensor
关键词 MNO2 敏感材料 室温固相反应 催化活性 MnO2 sensitive materials solid-state reaction catalytic activity
  • 相关文献

参考文献14

  • 1KOICHI E, HIROMICHI A. Low-Temperature Oxidation of Methane over Pd-Based Catalyst s: Effect of Support Oxide on the Combustion Activity. Applied CatalysisA : General, 2001, 222 : 359 - 367.
  • 2MUELLER C A, MACIEJEWSKI M, KOEPPEL R A, et al. Combustion of Methane over Palladium/Zirconia: Effect of Pd-Particle Size and Role of Lattice Oxygen. Catal Today, 1999, 47 ( 124 ) : 245 - 252.
  • 3BURCH R, LOADER P K. Investigation of Pt/ Al2O3 and Pd/ Al2O3 Catalysts for the Combustion of Methane at Low Concentrations. Appl Catal B, 1994, 5 (122) : 149 -164.
  • 4CIUPARU D, PFEFFERLE L D. Methane Combustion Activity of Supported palladium Catalysts after Partial Reduction. Appl Catal A, 2001, 218 (122) : 197 -209.
  • 5MiCHEUD C, MARECOT P, GUERIN M, et al. Preparation of Alumnia Supported Palladium-Platinum Catalysts by Surface Redox Reactions Activity for Complete Hydro-carbon Oxidation. Applied Catalysis A : General, 1998, 171:229-239.
  • 6DELPHINE R, PAT RICK G, MICHEL P, et al. Catalytic Behaviour of Cl-Free and Cl-Containing Pd/ Al2O3 Cata-lysts in the Total Oxidation of Methane at Low Temperature. Applied Catalysis A: General, 2000, 203 : 27 - 45.
  • 7CHOUDHARY V R, UPHADE B S, PATASKAR S G, et al. Low Temperature Complete Combustion of Methane over Mn ^- , Co^- , and Fe-Stabilized ZrO2. An gew Chem Int Ed Engl, 1996, 35 (20) : 2393 - 2395.
  • 8王军威,田志坚,徐金光,徐云鹏,徐竹生,林励吾.甲烷高温燃烧催化剂研究进展[J].化学进展,2003,15(3):242-248. 被引量:39
  • 9ARTIZZU-DUART P, MILLET J M, GUILHAUME N, et al. Catalytic Combustion of Methane on Substituted Barium Hexaaluminates. Catal Today, 2000, 59 (1 -2): 163-177.
  • 10YEH T F, LEE H G, CHU K S, et al. Characterization and Catalytic Combustion of Methane over Hexaaluminates. Mater Sci Eng A, 2004, 384 (1-2): 324-330.

二级参考文献65

  • 1缪建英 杨乐夫 陈笃慧.应用化学(App1.Chem.),1998,15(4):37-40.
  • 2Pfefferle L D, Pfefferle W C. Catal. Rev.-Sci. Eng.,1987, 29:219-267.
  • 3Harrison B K, Ernst W R. Combust. Sei. Tech. , 1978,19:31-41.
  • 4Oh S H, Mitchell P J, Siewert R M. Catalytic Contral of Air Pollution, ACS Symposium Series, 1992, 121 495-509.
  • 5Baran E J. Catal. Taday, 1990, 8; 133-152.
  • 6Arai H, Yamada T, Eguchi K, et al. Appl. Catal. A,1986, 26: 265-276.
  • 7Rayadurni J, Carbeny J J. J. Catal. , 1994,147:594-597.
  • 8Jernigan G G, Somorjai G A. J. Catal. , 1994,147: 567-577.
  • 9Ismagilov Z R, Kerzhentsev M A. Catal. Rev. -Sci. Eng. ,1990 32:51-103.
  • 10Bosch H, Janssen F. Catal. Today, 1988, 2:369-521.

共引文献38

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部