气体雾化制备Fe-Ga合金粉末的微结构及磁致伸缩性能

MICROSTRUCTURE AND MAGNETOSTRICTION OF Fe-Ga POWDERS PREPARED BY GAS ATOMIZATION

为改善Fe-Ga合金的高频特性,采用黏结工艺制备Fe-Ga磁致伸缩复合材料.探索采用气体雾化法制备Fe_(81)Ga_(19)合金粉末,利用EDS,SEM,XRD和DTA研究粉末颗粒的基本特性.结果表明,雾化粉末颗粒球形度好,成分与目标成分接近,大部分颗粒内部为多晶体,颗粒以A2相为主,且含有少量DO_3相;经800℃热处理后,颗粒中有大量L1_2相析出,保温8 h,炉冷样品含有大量单晶颗粒.利用Fe_(81)Ga_(19)合金粉末和黏结剂制备黏结复合材料,粒径<25μm的热处理粉末颗粒制备黏结样品的饱和磁致伸缩值最大,为6.4×10^(-5).

The magnetostrictive composite material such as Terfenol-D,is composed of magnetostrictive particles dispersed within a polymer matrix,which is used to bind these particles to a relatively tough material,and the binder creates an insulating layer between the particles which increases the receptivity and reduces eddy current losses at high frequencies operation.Hong et al. reported that the maximum magnetostriction of 5.4×10^（-5） was obtained in a composite made by mixing the spherical Fe-Ga particles prepared by spark erosion in liquid Ar with epoxy of 48%volume fraction and curing in a magnetic field.Gaudet et al.investigated firstly the Fe-Ga powders prepared by mechanical alloying.Their results suggested that a disordered bcc A2 phase with no indication of any ordered DO_3 phase was observed in these powders.Unfortunately,in their report,they also did not describe how to bond powders into a composite and how its magnetostrictive performance was.In present study,the spherical Fe-Ga particles were prepared by gas atomization and their microstructures were investigated by XRD,DTA,SEM and EDS.The results demonstrate that the Ga concentration of gas-atomized particles is near the nominal composition of Fe_（81）Ga_（19） and most of particles are poly-crystalline mainly composed of A2 phase and a small amount of ordered DO_3 phase.It is found that L1_2 phase appeared in the Fe_（81）Ga_（19） annealed powders is detrimental to improvement of magnetostriction. However,many single crystals were obtained due to crystallization during annealing,which is beneficial to increasing the magnetostriction.The bonded magnetostrictive composite was prepared by magnetically aligning compression molding Fe_（81）Ga_（19） powders and epoxy.The maximum saturation magnetostriction of 6.4×10^（-5） is obtained in the composite containing annealed powders.