摘要
高铁酸钾是强氧化剂,在进行氧化反应时,K2FeO4较难进入有机相。以环己醇氧化合成环己酮为模型反应,通过试验探索出了超稳分子筛-磷酸-K2FeO4(相转移催化剂)所组成的体系在有机溶剂中可快速氧化环己醇为环己酮。
Potassium ferrate,a new green oxidant,has powerful oxidization and high selectivity,but it is difficult to solve in organic solvent in the oxidation.So the oxidation of cyclohexanol to cyclohexanone by potassium ferrate was studied,the catalyst system of ultrastable zeolite,phosphoric acid and potassium ferrate could accelerate oxidation cyclohexanol to cyclohexanone and showed good oxidation ability in the organic solvent.
出处
《化学工业与工程》
CAS
2009年第6期497-499,共3页
Chemical Industry and Engineering
基金
黑龙江省自然科学基金项目
编号:B2007-06
关键词
K2FeO4
环己醇
超稳分子筛
磷酸
potassium ferrate（K2FeO4）
cyclohexanol
ultrastable zeolite
phosphoric acid
