新型卟啉衍生物的合成、结构表征及其电化学性质的研究

Synthesis, Structure Characterization of New Porphyrin Derivatives and Studies on Their Electrochemical Properties

以合成的[5-(4-溴苯基)-10,15,20-三苯基卟啉]锌为底物,通过Stille偶联的方法合成5-(4'-氨基-4-联苯基)-10,15,20-三苯基卟啉、[5-(4'-氨基-4-联苯基)-10,15,20-三苯基卟啉]锌配合物以及[5-(4'-甲硫基-4-联苯基)-10,15,20-三苯基卟啉]锌配合物,用UV,NMR,IR和MS对其结构进行了表征,研究了部分化合物的荧光和电化学性质.

Using [5-（4-bromophenyl）-10,15,20-triphenylporphinato]zinc（Ⅱ） as the substrate, 5-（4＇-aminobiphenyl-4-yl）- 10,15,20-triphenylporphyrin, [5-（4＇-amino-biphenyl-4-yl）- 10,15,20-triphenylporphinato]zinc（Ⅱ） and [5-（4＇-methylthio-biphenyl-4-yl）-10,15,20-triphenylporphinato]zinc（Ⅱ） were synthesized by Stille coupling reaction. The structures of all the products were characterized by UV, NMR, IR, MS techniques. The fluorescence and electrochemical properties of some compounds were also studied.