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由Co^(2+)和OH^-形成的移动化学反应界面实验的报道 被引量:1

A REPORT ON THE EXPERIMENTS OF MOVING CHEMICAL REACTION BOUNDARY (MCRB)FORMED BY Co 2+ AND OH -*
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摘要 进行了由Co2+和OH-形成的“移动化学反应界面”的实验.实验中,观察了界面移动速度(μαβthe)对比.通过改变Co2+和OH-的浓度和反应管中电场强度等参数,总共完成了26次实验.统计分析表明:μαβobs和μαβthe的相关系数是0.997,μαβthe和μαβobs之间的线性回归方程是μαβthe=1.044μαβobs+0.136.结果显示:实验观察的界面移动速度(μαβibs)与理论预测的速度(μαβthe)之间定量吻合.所以,实验直接证明了移动化学反应界面理论的有效性. We performed the experiments of moving chemical reaction boundary(MCRB)formed by cobaltic and hydroxylions, and compared the experimental velocity(μ αβ obs )of MCRB with the theoretical veloctiy(μ αβ the ). After all of 26 runs were finished, the statistics analyses were given. The analytic data shown the the correlation coefficient between μ αβ obs and μ αβ the is 0.9971, the linear regression equation between μ αβ the and μ αβ obs is μ αβ the =1.0435 μ αβ obs +0.1358. Therefore, the results the experimental velocity is quantitatively in agreement with the theoretical velocity, and the validity of the MCRB theory is directly tested by the experiments.
出处 《安徽师大学报》 1998年第3期222-226,共5页
关键词 界面 钴离子 氢氧根离子 移动化学反应 线性回归 boundary\ electrolyte\ electromigration\ electrophoresis
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