聚合物溴酸根在NaHSO_3作用下的氧化性能研究

Study on Polymersupported Bromate Ion Oxidizer With Sodium Bisulfite

强碱离子交换树脂支载溴酸根得到聚合物溴酸根氧化剂，在ＮａＨＳＯ３作用下，具有良好的氧化性能，分别将伯醇和简单醚氧化为酯，仲醇为酮，α，ω二醇和环醚为内酯，硫（或硒）醇为二硫（硒）化合物，并得到较好的收率．

Polymersupported bromate ion oxidizer was prepared from strong basic ionexchange resin with sodium bromate The primary alcohols and simply ether were effectly oxidized to ester, second alcohols to ketone, α,ω diols and cycle ether to lactone, thoil and selenol to disulfide and diselenide in the presence of NaHSO 3 with polymersupported bromate ion oxidizer Higher yields were obtained