非氟磺化芳香聚合物质子传输膜材料的研究进展

Development of the Sulfonated non-Fluorinated Aromatic Polymers for Proton Conductive Membranes

作者结合自己的研究工作,综述了磺化聚芳醚、聚酰亚胺、聚吡咙、聚苯等非氟芳香聚合物质子传输膜材料的国内外研究发展现状,系统介绍和讨论了上述材料设计、制备,膜微观形态,以及结构与性质的关系,指出了制约这类材料性能和发展的因素,并对未来的研究和发展提出了新的设想。

Based on the authors＇ research work, this paper reviewed the recent progress of the sulfonated nonfluorinated aromatic polymers for proton conductive membranes, such as sulfonated poly （ arylene ether） s, sulfonated polyimides, sulfonated poly [bis （benzimidazobenzisoquinolinones） ], and sulfonated poly （phenylene） s. The design, the preparation of these materials, and the relationship between the micro-morphology and properties of membranes were discussed in detail. Meanwhile, this review indicated the factors that influenced the development of these materials. Finally, the trend of the development of these materials had also been highlighted.