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溶剂精制对焦化蜡油和催化回炼油催化裂化反应性能的影响 被引量:8

INFLUENCE OF SOLVENT REFINING ON CATALYTIC CRACKING PERFORMANCE OF INFERIOR COKER GAS OIL AND HEAVY CYCLE OIL
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摘要 采用糠醛对辽河超稠原油直接延迟焦化得到的劣质焦化蜡油及其与催化回炼油的混合油进行溶剂精制,并在连续反应-再生催化裂化中型实验装置中进行了溶剂精制前后劣质焦化蜡油及其与催化回炼油混合油的催化裂化反应。结果表明,在精制油收率67%~70%的条件下,溶剂精制法可脱除劣质焦化蜡油中78%~85%的氮和36%~39%的芳烃、胶质及沥青质。劣质焦化蜡油及其与催化回炼油的混合油溶剂精制后,其催化裂化反应转化率大幅度提高。精制油的催化裂化反应性能优于辽河渣油催化裂化(RFCC)原料,与RFCC原料掺炼后,轻质油产率提高,生焦率下降,产品质量明显改善。 The solvent refining of inferior coker gas oil (CGO) derived from Liaohe ultra-viscosity crude and its mixture with FCC heavy cycle oil (HCO) was carried out by furfural. These solvent refined oils were catalytically cracked in a FCC pilot plant. The experimental results showed that after solvent refining with 67%- 70% refined oil yield, the 78%--85% denitrification rate, and 36%--39% removal rate of polycyclic aromatic, resin and asphaltene for the inferior CGO were obtained. The catalytic cracking conversions of the inferior CGO and CGO-HCO mixture after solvent refining were obviously increased. These refined oils were superior to the Liaohe RFCC feedstock, and blending them into RFCC feedstock led to an increase of light oil yield, a decrease of coke, and better products quality in catalytic cracking reaction.
出处 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2009年第6期777-783,共7页 Acta Petrolei Sinica(Petroleum Processing Section)
基金 国家杰出青年科学基金项目(20725620)资助
关键词 焦化蜡油 回炼油 催化裂化 溶剂精制 转化率 coker gas oil(CGO) heavy cycle oil(HCO) catalytic cracking solvent refining conversion
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  • 1孙大权,廖克俭,闫锋,魏毅,霍开富.辽河超稠原油加工方案的初步研究[J].石油炼制与化工,2000,31(11):21-24. 被引量:11
  • 2陈文艺,王海彦,关毅达.大庆、胜利和辽河焦化蜡油性质与组成对比及加工利用研究[J].石油化工高等学校学报,2000,13(4):18-24. 被引量:14
  • 3CAO Z, HOU B, CHEN W, et al. Composition and properties of Chinese coker gas oil [J]. Petroleum Science and Technology, 2007, 25(6): 705-717.
  • 4WANG G, XU C M, GAO J S. A novel conceptional process for residue catalytic cracking and gasoline reformation dual-reactions mutual control[J]. Applied Catalysis A: General, 2008, 341(1--2): 98--105.
  • 5WOODS J R, KUNG J, PLEIZIER G. Characterization of a coker gas oil fraction from Athabasca oilsands bitumen[J]. Fuel, 2004, 83(4) :1907--1914.
  • 6YOUNG GW. Fluid catalytic cracker catalyst design for nitrogen tolerance [ J ]. Journal Physics Chemistry, 1986, 90(20): 4894--4900.
  • 7SCHERZER J, MCARTHUR D P. Tests show effects of nitrogen compounds on commercial fluid cat cracking catalysts[J]. Oil& Gas Journal, 1986, 84(43); 76--82.
  • 8于道永,徐海,阙国和,王宗贤.碱氮化合物喹啉催化裂化转化规律的研究[J].燃料化学学报,2004,32(1):43-47. 被引量:20
  • 9袁起民,王屹亮,李春义,杨朝合,山红红.焦化蜡油催化裂化产物氮分布的研究[J].燃料化学学报,2007,35(3):375-379. 被引量:24
  • 10WOJCIECHOWSKI B W, CORMA A. Catalytic Cracking: Catalysts, Chemistry, and Kinetics, Chemical Industries[M]. New York: Marcel Dekker, 1986.

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