摘要
一价Cu催化下多卤代物和烯烃的加成反应具有原料易得、回收率高、反应专一性好等优点及很大应用价值。该反应用于农药中间体的合成,对农药的研制和开发有促进作用,已成为工业生产和实验室制备有机化合物的捷径。介绍了该反应的类型及其在农药中间体合成中的应用。
The literatureas on the cuprous catalyzed additions of polyhalogenated compounds to olefins are critically reviewed. This kinds of reactions are featured of the cheap materials, high recovery and exclusive product. They can be applied to the synthesis of pesticide intermediates, which become a simple way for the synthesis of some organics on the commercial and laboratorial scale.
关键词
卤代物
烯烃
氧化
还原
加成反应
亚铜
催化
polyhalogenated compounds olefins redox addition pesticide intermediate