摘要
A simple but effective doping method, immersion method, was presented. Rare earth complexes [Na3Tb(DPA)3·9H2O and Na3Eu(DPA)3·9H2O] were introduced into porous silicon (PS), where H2DPA is 2,6-dicarboxy pyridine acid. Rare earths were proved to dope into PS effectively by photoluminescence (PL) and X-ray energy dispersive spectroscopy (EDS). And the prepared hybrid samples of PS/RE were found to emit intense room-temperature red and green luminescence while the luminescence of porous silicon are almost thoroughly quenched.
A simple but effective doping method, immersion method, was presented. Rare earth complexes [Na3Tb(DPA)3·9H2O and Na3Eu(DPA)3·9H2O] were introduced into porous silicon (PS), where H2DPA is 2,6-dicarboxy pyridine acid. Rare earths were proved to dope into PS effectively by photoluminescence (PL) and X-ray energy dispersive spectroscopy (EDS). And the prepared hybrid samples of PS/RE were found to emit intense room-temperature red and green luminescence while the luminescence of porous silicon are almost thoroughly quenched.
基金
Funded by the Natural Science Foundations of Guangdong Province (No. 06300901),China
the Application and Innovation Project of Ministry of Public Security, China(No.2007 YYCXUDST 076)