摘要
The two title complexes [{Cd（IBG-CH3）（4,4＇-bipy）（H2O）2}·NO3]n 1 and [{Cd（IBG）- （4,4＇-bipy）（H2O）2}·2H2O]n 2 （H2IBG = isophthaloylbisglycine and 4,4＇-bipy = 4,4＇-bipyridine） have been synthesized and characterized by single-crystal structure determination,IR and TG analyses. Complex 1 crystallizes in monoclinic,space group C2/c with a = 27.221（2）,b = 11.6093（7）,c = 16.3571（9）A,V = 5149.2（6） A^3,Z = 8,C23H23N5O11Cd,Mr = 657.86,Dc = 1.697 g/cm^3,F（000） = 2656.00,μ（MoKα） = 0.919 mm^-1,the final R = 0.0478 and wR = 0.0882 for 3728 observed reflections with I 〉 2σ（I）. Complex 2 crystallizes in triclinic,space group Pī with a = 9.0940（4）,b = 11.6852（5）,c = 13.1119（6）A,V = 1230.26 A^3,Z = 2,C22H26N4O10Cd,Mr = 618.87,Dc = 1.671 g/cm^3,F（000） = 628.0,μ（MoKα） = 0.951 mm^-1,the final R = 0.0567 and wR = 0.1124 for 3713 observed reflections with I 〉 2σ（I）. In both structures,the CdII metal centers are coordinated by seven atoms to form a distorted pentagonal bipyramidal geometry.
The two title complexes [{Cd（IBG-CH3）（4,4＇-bipy）（H2O）2}·NO3]n 1 and [{Cd（IBG）- （4,4＇-bipy）（H2O）2}·2H2O]n 2 （H2IBG = isophthaloylbisglycine and 4,4＇-bipy = 4,4＇-bipyridine） have been synthesized and characterized by single-crystal structure determination,IR and TG analyses. Complex 1 crystallizes in monoclinic,space group C2/c with a = 27.221（2）,b = 11.6093（7）,c = 16.3571（9）A,V = 5149.2（6） A^3,Z = 8,C23H23N5O11Cd,Mr = 657.86,Dc = 1.697 g/cm^3,F（000） = 2656.00,μ（MoKα） = 0.919 mm^-1,the final R = 0.0478 and wR = 0.0882 for 3728 observed reflections with I 〉 2σ（I）. Complex 2 crystallizes in triclinic,space group Pī with a = 9.0940（4）,b = 11.6852（5）,c = 13.1119（6）A,V = 1230.26 A^3,Z = 2,C22H26N4O10Cd,Mr = 618.87,Dc = 1.671 g/cm^3,F（000） = 628.0,μ（MoKα） = 0.951 mm^-1,the final R = 0.0567 and wR = 0.1124 for 3713 observed reflections with I 〉 2σ（I）. In both structures,the CdII metal centers are coordinated by seven atoms to form a distorted pentagonal bipyramidal geometry.
基金
Supported by the Key Subject of Huangshan University (No. 2007xkjq013)
