手性二胺配体在不对称催化反应中的应用
Chiral diamine ligands and their applications in asymmetric reactions
摘要
手性二胺类配体因其良好的催化活性和对映选择性得到了广泛研究。该文综述了近期手性二胺配体在不对称反应中的应用进展。
Chiral diamine ligands have been widely studied in asymmetric reactions for their good reactivity and excellent enantioselectivity. This review covers the recent applications of chiral diamine ligands in asymmetric reactions.
出处
《中国药物化学杂志》
CAS
CSCD
2009年第6期476-485,共10页
Chinese Journal of Medicinal Chemistry
关键词
手性二胺
不对称催化
不对称反应
chiral diamine
asymmetric catalysis
asymmetric reaction
参考文献30
-
1CORTEZ N A,AGUIRRE G,SOMANATHAN R. Water-soluble chiral monosulfonamide-cyclohexane1,2-diamine-RhCp^* complex and its application in the asymmetric transfer hydrogenation(ATH) of ketones[J]. Tetrahedron Lett,2007,48 (25) :4335 - 4338.
-
2CORTEZ N A,AGUIRRE G, SOMANATHAN R. New heterogenized C2-symmetric bis( sulfonamide)- cyclohexane-1,2-diamine-Rh III Cp^* complexes and their application in the asymmetric transfer hydrogenation(ATH) of ketones in water[ J ]. Tetrahedron Lett,2009,50(19) :2228 - 2231.
-
3CORTEZ N A,AGUIRRE G, SOMANATHAN R. Ruthenium( II ) and rhodium( II ) catalyzed asymmetric transfer hydrogenation (ATH) of acetophenone in isopropanol and in aqueous sodium formate using new chiral substituted aromatic monosulfonamide ligands derived from ( IR,2R)- diaminocyclohexane [ J ]. Tetrahedron: Asymmetry, 2008, 19 (11) :1304 - 1309.
-
4YIM A S Y, WILLS M. Asymmetric transfer hydrogenation using amino acid derivatives;further studies and a mechanistic proposal[ J ]. Tetrahedron,2005, 61(33) :7994 -8004.
-
5MARTINS J E D, MORRIS D J, WILLS M. Further 'tethered' Ru(II) catalysts for asymmetric transfer hydrogenation (ATH) of ketones; the use of a benzylic linker and a cyclohexyldiamine ligand[ J ]. J Org Chem,2008,693 (23) :3527 - 3532.
-
6GUO R W,ELPELT C,MORRIS R H. A modular design of mtllenium catalysts with diamine and BINOL derived phosphinite ligands that are enantiomerically-matched for the effective asymmetric transfer hydrogenation of simple ketones [ J ]. Chem Commun,2005 (24) :3050 - 3052.
-
7MAERTEN E, AGBOSSOU-NIEDERCORN F,CASTANET Y. Preparation of pyridinyl aryl methanol derivatives by enantioselective hydrogenation of ketones using chiral Ru (diphosphine) (diamine) complexes. Attribution of their absolute configuration by ^1 H-NMR spectroscopy using Mosher's reagent. [ J ]. Tetrahedron ,2008 ,64 (37) : 8700 - 8708.
-
8LI C Q,XIAO J L. Asymmeaic hydrogenation of cyclic imines with an ionic Cp^* Rh(Ⅲ) catalyst[J]. J Am Chem Soc,2008,130(40) : 13208 - 13209.
-
9MARTINS J E D, CLARKSON G J, WILLS M. Ru (Ⅱ) complexes of N-alkylated TsDPEN ligands in asymmetric transfer hydrogenation of ketones and imines[ J]. Org Lett,2009,11 (4) :847 -850.
-
10BISAI A, SINGH P K, SINGH V K. Enanfioselective diethylzinc addition to aldehydes catalyzed by Ti (IV) complex of unsymmetrical chiral bis ( sulfonamide) ligands of trans-cyclohexane 1,2- diamine [ J ]. Tetrahedron,2007,63 (3) : 598 - 601.
-
1赵明珠,姜志辉,蔡瞻,张大志.脯氨酸衍生物类有机催化剂的研究进展[J].药学实践杂志,2012,30(1):19-24.
-
2史清华,王玉玲,宋宏锐.不对称烷基化反应在药物及生物活性化合物合成中的应用[J].中国药物化学杂志,2009,19(6):463-475.
-
3卢作勇.不对称全合成技术(二)——甲酰化的不对称合成[J].中国制药信息,2004,20(12):15-18.
-
4石映红.“手性”和不对称催化反应简介及发展[J].科技创新导报,2011,8(16):221-221. 被引量:1
-
5陈亿新,刘天穗,刘汝锋,李国良,李月明,曾志.手性药物技术与展望[J].广州大学学报(自然科学版),2002,1(1):39-43. 被引量:17
-
6手性技术[J].中国科技信息,2002(16):15-15.
-
7贾美荣,杨康辉,江余祺,孙乐乐,徐文方.手性氯霉胺及其衍生物的应用进展[J].中国药物化学杂志,2010,20(6):543-549. 被引量:3
-
8尤思路.手性药物及其不对称催化合成的研究进展[J].西南军医,2010,12(1):109-111. 被引量:7
-
9马小魁.微生物酶转化合成手性药物的研究进展[J].微生物学杂志,2006,26(5):71-74. 被引量:7
-
10申永存,金晶,张毅,杨晓婷,严罗一.联萘二甲酸的合成与拆分[J].武汉理工大学学报(交通科学与工程版),2012,36(4):833-835.