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Density, Viscosity, and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether + Water from 293.15 to 333.15 K at Atmospheric Pressure 被引量:5

Density, Viscosity, and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether + Water from 293.15 to 333.15 K at Atmospheric Pressure
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摘要 Densities and viscosities were measured as a function of composition for binary liquid mixture of diethylerie glycol monoethyl ether [CH3CH2O(CH2)2O(CH2)2OH] + water from 293.15 to 333.15 K at atmospheric pressure, with a capillary pycnometer and Ubbelohde capillary viscometer respectively. From the experimental data, the excess molar volume V^E, viscosity deviation △η, and the excess energy of activation for viscous flow △G^*E were calculated. These data were correlated by the Redlich-Kister type equations to obtain the coefficients and standard deviations. The results showed a strong molecular interaction between diethylene glycol monoethyl ether and water. 密度和粘性为 diethylene 乙二醇的二进制液体混合作为作文的一个函数被测量单音的乙醇醚[ CH <sub>3</sub > CH <sub>2</sub > O ( CH <sub>2</sub>)<sub>2</sub > O ( CH <sub>2</sub>)<sub>2</sub >哦]从在气压的 293.15~333.15 K 的+水,与毛状的比重瓶和厄布洛德毛状的粘度计分别地。从试验性的数据,过量臼齿的体积 V <sup > E </sup>, 粘性偏差 &#x394; &#x3b7;,并且激活为的过量精力粘滞流动 &#x394; G <sup>*E</sup> 被计算。这些数据被 Redlich-Kister 类型方程相关获得系数和标准差。结果显示出在 diethylene 乙二醇之间的一个强壮的分子的相互作用单音的乙醇醚和水。
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第6期1009-1013,共5页 中国化学工程学报(英文版)
关键词 DENSITY VISCOSITY diethylene glycol monoethyl ether binary mixture excess molar volume viscosity deviation 乙二醇乙醚 粘度测定 水煤浆 密度 二元 毛细管粘度计 分子间相互作用 常压
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