摘要
本文导出了描述理想气固吸附平衡的热力方程。吸附平衡常数具有热力学性质,从不同温度的吸附平衡常数可以得到积分吸附热。
A thermodynamic equilibrium equation is set up for ideal gas-solid adsorption.Adsorption equilibrium constant has thermodynamic properties.The integral adsorption heat can be acquired from the adsorption equilibrium constants at different temperatures.The ideal equilibrium condition of the gas-solid adsorption can be obtained from ln-ln adsorption isotherm.
关键词
气固吸附
热力学平衡
气固界面
化学吸附
gas-solid adsorption,thermodynamic equilibrium,Freundlich isothermal equation