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电池级Co_3O_4前驱体的制备实践

Preparation of Battery-grade Co_3O_4 Precursor
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摘要 研究了合成Co3O4前驱体的几个影响因素。实验选用氯化钴作为原料,碳酸钠作沉淀剂,Co离子浓度为60~70g/L,氯化钴/碳酸钠(摩尔比)比值在0.60-0.70之间,加液方式选择将沉淀剂加入氯化钴液中,沉淀时pH值控制在9.0~9.6。实验表明,在上述条件下,可以获得较好的Co3O4前驱体。 Some factors which affected the synthesis of Co304 precursor were studied. Cobalt chloride was selected as raw material, sodium carbonate as precipitant, the concentration of cobalt ion was 60 -70 g/L, the ratio( mol ratio) of cobalt chloride and sodium carbonate was among 0.60 - 0.70, precipitant was added into cobalt chloride solution and pH value was controled among 9.0 - 9.6 during precipitation, better Co3O4 precursor can be obtained.
出处 《矿冶工程》 CAS CSCD 北大核心 2009年第6期92-95,共4页 Mining and Metallurgical Engineering
基金 中南林业科技大学人才引进项目
关键词 四氧化三钴 碳酸钴 氯化钴 前驱体 形貌 Co3O4 cobalt carbonate cobalt chloride precursor shape
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参考文献13

  • 1周健,宁顺明,习小明.电子级Co_3O_4制备方法及其进展[J].矿冶工程,2005,25(2):39-42. 被引量:5
  • 2郭炳昆,李新海,杨松青.化学电源-电池原理及制造技术[M].长沙:中南工业大学出版社,2001.
  • 3Zhenyong, Yuon. Synthesis and Electrochemical Performance of Nanosized Co3O4 [ J ]. Materials Chemistry and Physics, 2003,79 : 1 - 4.
  • 4Heman L. Crystallit and Microstranis of Co3O4 Derived from CoOH and Co(OH) 2 [ J]. Journal of solid state chemistry, 1985,59:388 - 392.
  • 5雷慧绪.电子工业用氧化钴、氧化镍粉末的生产方法[P].中国专利,1114639A.1996-01-10.
  • 6孙思修 张卫民 杨延钊.Co3O4纳米粉体的制备方法[P].中国专利:1344682A.2002-04-17.
  • 7戴振华.Co3O4的制造方法[P].中国专利:1376638A.2002-10-30.
  • 8庄稼,迟燕华,王曦,王清成,杨定明,贾殿赠.室温固相反应制备纳米Co_3O_4粉体[J].无机材料学报,2001,16(6):1203-1206. 被引量:38
  • 9彭文杰,李新海,王云燕,王志兴,郭华军.固相合成条件对LiCoO_2结构与形貌的影响[J].中南大学学报(自然科学版),2004,35(1):59-64. 被引量:10
  • 10曾福兴.一种高纯度四氧化三钴的制造方法[P].中国专利,1587069A.2004-06-27.

二级参考文献44

  • 1Jinzhang Gao, Yanchun Zhao, Wu Yang, Jianniao Tian, Fei Guan. and Yongjun MaChemistry and Chemical Engineering College, Northwest Normal University, Lanzhou 730070, China.Sol-gel preparation and characterization of Co_3O_4 nanocrystals[J].Journal of University of Science and Technology Beijing,2003,10(1):54-57. 被引量:13
  • 2李普良,徐舜,习小明.锂离子电池正极材料LiCoO_2合成方法及其掺杂研究进展[J].矿冶工程,2004,24(1):84-88. 被引量:10
  • 3庄稼,张卫华,郑丽敏,忻新泉.固相配位化学反应研究——LⅦ.阴离子盐KY(Y=Cl,Br,I,CN,SCN)对[Co(NH_3)_4CO_3]Cl热分解的影响[J].无机化学学报,1993,9(3):260-265. 被引量:8
  • 4[1]PENG Z S,WAN C R,JIANG C Y.Synthesis by sol-gel process and characterization of LiCoO2 cathode materials [J].Journal of Power Sources,1998,72(2):215-220.
  • 5[2]Akimoto J,Gotoh Y,Oosawa Y.Synthesis and structure refinement of LiCoO2 single crystals [J].Journal of Solid State Chemistry,1998,141(1):298-302.
  • 6[3]Jeong E D,Won M S,Shim Y B.Cathodic properties of a lithium-ion secondary battery using LiCoO2 prepared by a complex formation reaction [J].Journal of Power Sources,1998,70(1):70-77.
  • 7[4]Kang S G,Kang S Y,Ryu K S,et al.Electrochemical and structural properties of HT-LiCoO2 and LT-LiCoO2 prepared by the citrate sol-gel method [J].Solid State Ionics,1999,120(1):155-161.
  • 8[5]Shao-Horn Y,Hackney S A,Johnson C S,et al.Structural feature of low-temperature LiCoO2 and acid-delithiated products [J].Journal of Solid State Chemistry,1998,140(1):116-127.
  • 9[6]Garcia B,Farcy J,Pereira-Ramos J P.Electrochemical properties of low temperature crystallized LiCoO2 [J].J Electrochem Soc,1997,144(4):1179-1184.
  • 10[7]Wolverton C,Zunger A.Prediction of Li intercalation and battery voltages in layered vs.cubic Lix CoO2 [J].J Electrochem Soc,1998,145(7):2424-2431.

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