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广州市白云山降水的化学特征及源解析 被引量:7

Chemical Characteristic and Source Assessment of Wet Precipitation at Mountain Baiyun,Guangzhou
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摘要 以2006年广州市白云山降水监测资料为基础,对其降水样品的化学特征进行了分析。结果表明,白云山降水样品pH值分布为3.04—6.41,雨量加权pH平均值为4.26,酸雨频率为70.2%,降水中的主要阳离子是Ca^2+和NH^+4分别占阳离子总量的46.4%和17.5%;主要阴离子为SO^2-4和NO^-3,分别占阴离子总量的59.0%和19.9%。相对酸度(FA)和中和因子(NF)计算结果表明,约有84.7%的降水酸度被碱性成分Ca^2+和NH^+4中和。利用富集系数方法,计算结果表明SO^2-4和NO^-3主要来源于人类活动,而Ca^2+和K^+主要来源于岩石/土壤风化。 The chemical characteristic of wet precipitation was studied at Mountain Baiyun, Guangzhou on the basis of monitoring data in 2006. The rainwater was typically acidic with a volume-weighted mean pH value of 4.26, which ranged from 3.04 to 6.41. 70.2% of the total samples had pH values less than 5.60. The percent contribution to anions for SO^2-4 and NO^-3 were 59.0% and 19.9% respectively. Ca^2+ was the highest concentration among the total cations with a contribution of 46.4 % , while NH^+4 presented 17.5%. Nearly 84.7% of the acidity of rainwater was neutralized by main alkaline cations, Ca^2+ and NH^+4. Enrichment factors of major ions were computed to assess possible sources of major ions. The results showed that SO^2-4 and NO^-3 were from anthropogenic activities, while Ca^2+ and K^+ from crust sources.
出处 《环境监测管理与技术》 2009年第6期20-23,共4页 The Administration and Technique of Environmental Monitoring
基金 广东省科学院分析测试基金资助项目(sf200804)
关键词 降水 化学特征 源估计 富集系数 中和因子 广州白云山 Wet precipitation Chemical characteristic Source assessment Enrichment factor Neutralization factor Mountain Baiyun, Guangzhou
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