期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

苯并咪唑金属铼(I)配合物的合成及发光性质的研究 被引量：4

Syntheses,properties of luminescent rhenium(I) complexes with benzimidazole ligands
下载PDF
导出
摘要 以过渡金属铼为中心金属离子,合成了2-(2-吡啶)苯并咪唑(HL1)和2,6-二(苯并咪唑)吡啶(HL2)配合物.该配合物荧光量子产率高、化学性质稳定,在固体状态下,最大发射峰分别是543nm、577nm,处在绿光和黄光区.其发光基理是基态金属离子电荷向激发态配体跃迁(MLCT),属于金属离子与配体间的dπ→π*(L)的跃迁发光. A kind of new material consisting of Re centralion and benzimidazole ligands had been deve loped.These novel luminescent complexes were synthesized.In the solid state,these complexes 1,and 2 have an emission maximum at 543,577 nm,respectively.They display yellow,green luminescence and have high luminescence quantum efficiency.The luminescent properties of Re （I） pyridyl-imidazole complex was also investigated,the assignment of emission was notable metal to ligand charge transfer （MLCT） process upon dπ→π＊（L） transition.
作者 岳淑美 边江鱼 唐艳茹 李娜
机构地区 长春师范学院化学学院
出处 《分子科学学报》 CAS CSCD 北大核心 2009年第6期427-430,共4页 Journal of Molecular Science
基金 国家教育部2008年重点资助项目(208034) 吉林省教育厅"十五"科学技术研究资助项目(2007163)
关键词 苯并咪唑 配合物 发光 最大发射峰 benzimidazole complexes luminescence emission maximum
分类号 O614 [理学—无机化学]
  • 相关文献

参考文献12

  • 1ADACHI C,BALDO M A,THOMPSON M E,et al.[J].J Appl Phys,2001,90(10) :5048-5051.
  • 2YANG W,SCHMIDER H,WU Q,et al. [J]. Inorg Chem,2000, (39) :2397-2402.
  • 3LIU S F, WU Q,SCHMIDER H L,et al. [J].J Am Chem Soe,2000, (122):3671-3678.
  • 4马东阁.白光有机发光二极管的最新进展[J].分子科学学报,2007,23(4):223-236. 被引量：12
  • 5SEWARD C, PANG J, WANG S. [J]. Eur J Inorg Chem,2002, (144) : 1390-1399.
  • 6LI Y Q,LIU Y,WANG Y,et al. [J].Chem Mater,2000, (12) :2672-2676.
  • 7LIU Y, GUO J H,ZHANG H D, et al. [ J]. Angew Chem Int Ed,2002, (41): 182-185.
  • 8ZHANG Z L,JIANG X Y,ZHU W Q,et al. [J]. Chin J Lumin,2005,26 (2) : 149-152.
  • 9NIU X,HUA Y L, WU K W,et al.[J] Chin J Lumin,2006,27 (4) :537-542.
  • 10ZHANG X J, XU Y N, SHI H H. [J].Chin J Lumin,2007,28(4):44-48.

二级参考文献31

  • 1Optoelectronics Industry Development Association (OIDA) 2002 Organic light-emitting diodes (OLEDs) for general illumination update 2002 Report August.
  • 2WANG C T, VANSLYKE S A [J]. Appl Phys Lett, 1987,51:913-915.
  • 3http://www.novale.com.
  • 4DANDRADE B W,FORREST S R. [J].Adv Mater,2004,16:1585-1595.
  • 5ZAKYA H. K. Organic electroluminescence[M]. New York: CRC Press, 2005.
  • 6DUGGAL A R, SHIANG J J, FOUST D F, et al. [J]. Appl Phys Less, 2002,80: 3470-3472.
  • 7http://www.osram-os. com.
  • 8MA J W,JIANG X Q,SCOTTP. [J]. Phys Lett A,2005,344(6):423-431.
  • 9SUN Y R,GIEBINK N C,KANNO H,et al. [J]. Nature,2006,440:908-912.
  • 10KANNO H,SUN Y R,FORREST S R. [J]. Appl Phys Lett,2006,89:143516.

共引文献11

同被引文献39

  • 1周庆华,杨频.1,3-双(2-苯并咪唑基)-2-氧杂丙烷与锌配合物的合成、晶体结构及其与DNA作用方式的研究[J].化学学报,2006,64(8):793-798. 被引量：25
  • 2Pope M, Kallmann H, Magnante P. Electroluminescence in Organic Crystals [J ]. Chem Phys,1963,38:2042-2043.
  • 3Shi J, Chen C H, Klubek K P. Organic Electroluminescent Elements for Stable Blue Electroluminescent Devices [P]. US: 5972247,1999-10-26.
  • 4Krzysztof D, Huang T, Chuen C, et al. Blue-Emitting Anthracenes with End-Capping Diarylamines[ J ]. Chem Mater,2002,14:3860-3865.
  • 5Tsai M L, Liu C Y, Chou T C, et al. Preparation and Luminescence Properties of Polymers Containing Dialkoxyacenes[ J ]. Chem Mater,2004,16:3373-3380.
  • 6Kim Y, Jeong H, Kim S, et al. High-Purity-Blue and High-Efticiency Electroluminescent Devices Based on Anthracene [ J ]. Adv Funct Mater,2005,15:1799-1805.
  • 7Lee T, Song K H, Jung I, et al. Silylene-spaced diphenylanthracene derivatives as blue-emitting materials[ J ]. J. Organomet Chem,2006,691:1887-1896.
  • 8Tao S L, Zhou Y C, Lee C S, et al. Highly Efficient Nondoped Blue Organic Light-Emitting Diodes Base on Anthracene-Triphenylamine Derivatives [ J ]. J Phys Chem C,2008,112:14603-14606.
  • 9Shih P I, Chuang C Y, Chien C H, et al. Highly Efficient Non-Doped Blue-Light-Emitting Diodes Based on an Anthrancene Derivative End-Capped with Tetraphenylethylene Groups[ J ]. Adv Funct Mater,2007,17: 3141-3146.
  • 10Fu W, Feng J K, Pan G B. Theoretical Study on the Third-order Nonlinear Optical Properties of a Series of Derived 9, 9′-Spirobifluorenes[ J ]. Journal of Molecular Structure (Theochem) 2001,545:157-165.

引证文献4

二级引证文献5

分子科学学报
2009年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部