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SiO/CNTs:新型锂离子电池负极材料 被引量：3

SiO/CNTs:A new anode composition for lithium-ion battery
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摘要 通过化学气相沉积方法原位制备了氧化硅/碳纳米管(SiO/CNTs)负极材料.扫描电镜(SEM)测试结果表明,碳纳米管沉积在氧化硅表面,形成笼状结构,将氧化硅粒子紧密包裹.SiO/CNTs负极材料的初始充放电容量分别为1171和789mAh/g,经过80次充放电循环后,可逆容量为500mAh/g.在循环过程中,碳纳米管和氧化硅之间的紧密接触使得SiO/CNTs复合材料保持了稳定的导电网络,循环性能得以提高. A new anode composition SiO/CNTs （carbon nanotubes） has been prepared by chemical vapor deposition （CVD） method. The results of scanning electron microscopy （SEM） confirm that CNTs deposit on small SiO particles, form a cage, and enwrap SiO particles tightly. SiO/CNTs anode composition exhibits an initial discharge and charge capacity of 1171 and 789 mAh/g, respectively, and maintains a reversible capacity of 500 mAh/g after 80 cycles. The improvement of the cyclic performance for SiO/CNTs composition is related to the maintaining of the electric network during cycling, which benefits from a tight contact between CNTs and SiO particles.
作者 任玉荣 瞿美臻 于作龙
机构地区 中国科学院成都有机化学研究所 吉林师范大学化学学院 中国科学院研究生院
出处 《中国科学（B辑）》 EI CSCD 北大核心 2009年第12期1593-1597,共5页 Science in China(Series B)
基金 中国科学院知识创新工程重要方向项目(批准号:KJCX2-YW-M01) 国家科学技术部重大科学研究计划项目课题(编号:2006CB932703) 成都中科来方能源科技有限公司资助
关键词 SiO/CNTs 化学气相沉积 复合材料 负极 锂离子电池 SiO/CNTs, CVD, composition, anode, Li-ion battery
分类号 TM912 [电气工程—电力电子与电力传动]
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参考文献14

  • 1Yamamoto H, Miyachi M, Kawai H S. Abstracts of the Electrochemical Society of Japan 2004 Spring Meeting, Yokohama, 2004:204.
  • 2YangJ, Takeda Y, Imanishi N, Capiglia C, Xie J Y, Yamamoto O. SiOx-based anodes for secondary lithium batteries. Solid State Ionics, 2002, (152-153): 125-129.
  • 3Miyachi M, Yamamoto H, Kawai H, Ohta T, Shirakata M. Analysis of SiO anodes for lithium-ion batteries. J Electrochem Soc, 2005, 152(10): A2089-A2091.
  • 4Beaulieu L Y, Eberman K W, Turner R L, Krause L J, Dahn J R. Colossal reversible volume changes in lithium alloys. Electrochem Solid-State Lett, 2001, 4(9):137-140.
  • 5Guo Z P, Wang J Z, Liu H K, Dou S X. Study of silicon/polypyrrole composite as anode materials for Li-ion batteries. J Power Sources, 2005, 146(1-2): 4413-451.
  • 6Kim B C, Uono H, Satou T, Fuse T, Ishihara T, Ue M. Cyclic properties of Si-Cu/carbon nanocomposite anodes for Li-ion secondary batteries. J Electrochem Soc, 2005, 152(3): A523-A526.
  • 7Lee H Y, Lee S M. Carbon-coated nano-Si dispersed oxides/graphite Composites as Anode material forLithium ion Batteries. Electrochem Commun, 2004, 6(5): 465-469.
  • 8Morita T, Takami N. Nano Si cluster-SiOx-C composite material as high-capacity anode material for rechargeable lithium batteries. J Electrochem Soc, 2006, 153(2): A425-A430.
  • 9Yang X, Wen Z, Xu X, Lin B, Huang S. Nanosized silicon-based composite derived by _in situ mechanochemical reduction for lithium ion batteries. J Power Sources, 2007, 164(2): 880-884.
  • 10Zhang T, Gao J, Zhang H P, Yang L C, Wu Y P, Wu H Q. Preparation and electrochemical properities of core-shell Si/SiO nanocomposite as anode material for lithium ion batteries. Electrochem Commun, 2007, 9(5): 886-890.

二级参考文献13

  • 1刘素琴,李世彩,黄可龙.Li_3V_2(PO_4)_3电极过程及其锂离子脱嵌动力学研究(Ⅰ)[J].化学学报,2007,65(1):10-16. 被引量：14
  • 2Idota Y,Kubota T,Matsufuji A,et al.Science,1997,276:1395-1397.
  • 3Idota Y,Mineo Y,Matsufuji A,et al.Denki Kagaku Oyobi Kogyo Butsuri Kagaku,1997,65:717-719.
  • 4Morimoto H,Tatsumisago M,Minami T.Electrochem.Solid-State Lett.,2001,4(2):A16-A18.
  • 5Dimov N,Fukuda K,Umeno T,et al.J.Power Sources,2005,147:227-233.
  • 6Hatchard T D,Dahn J R.J.Electrochem.Soc.,2004,151:A1628-A1635.
  • 7Yang J,Takeda Y,Imanishi N,et al.Solid State Ionics,2002,152-153:125-129.
  • 8Nagao Y,Sakaguchi H,Honda H,et al.J.Electrochemical Society,2004,151(10):A 1572-A 1575.
  • 9Miyachi M,Yamamoto H,Kawai H,et al.J.Electrochem.Soc.,2005,152:A2089-2091.
  • 10Klausnitzer B.Thesis for the Doctorate of University of Ulm.,2000..

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中国科学（B辑）
2009年 第12期

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