含钒无机有机杂化材料的合成、结构与性质

Synthesis,Structures and Properties of Inorganic-Organic Hybrid Polyoxovanadate

含钒无机有机杂化材料的结构复杂多样,在吸附、氧化还原、电化学、催化、光学、磁学以及多孔、手性材料研究等方面应用前景广阔,引起人们广泛关注。本文综述了含钒无机有机杂化材料的研究的最新进展,介绍了合成含钒无机有机杂化材料的主要方法,按照有机组分与无机骨架作用的方式分类总结了含钒无机有机杂化材料的结构,介绍了其在离子交换、电化学、磁学、光学、催化等方面的应用,并展望了该类材料的研究前景和意义。

Inorganic-organic hybrid polyoxovanadate have various structures,and considerable efforts have been devoted to the research of these compounds due to their wide potential applications to material science as adsorption,redox,electronic,catalytic,luminescent,magnetic,porous,and chiral materials.The research progress of inorganic-organic hybrid polyoxovanadate are reviewed in this paper.The synthesis methods of these complexes are introduced.The structures are summarized according to the mode of organic components and inorganic framework.The potential applications in ion exchange,electrochemistry,magnetism,luminescent material and catalyst are commented.The research of these materials are also prospeted.