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乙醇汽油发动机非常规排放及其催化转化的研究 被引量:22

Unregulated Emissions and Their Three-Way Catalytic Conversion of a Spark Ignition Engine Fueled with Ethanol-Gasoline
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摘要 利用气相色谱-氦离子化快速检测方法,研究了一台多点电喷汽油机分别燃用乙醇汽油混合燃料(乙醇的体积分数分别为0%、10%、20%和85%,记为E0、E10、E20和E85)时的非常规醇醛排放特性及其催化转化特性.研究结果表明:与汽油机相比,E10和E20混合燃料发动机的甲醛、乙醛和乙醇排放随乙醇掺混比的增加而增加,而E85混合燃料发动机的甲醛、乙醛排放增幅略小,约为E0发动机的1.6倍和2.4倍,乙醇排放却大幅增加,约为E10混合燃料发动机的35倍;随负荷的增加,乙醛排放整体呈增加的趋势,E10和E20混合燃料发动机的乙醇排放降低,而E85混合燃料发动机的乙醇排放却增加;普通的三效催化器对乙醛、乙醇排放的转化效率均在75%以上,但对甲醛的转化效果不佳,对E20和E85混合燃料发动机甲醛排放的转化效率低于30%. Four typical ethanol-gasoline blends,E0,E10,E20 and E85,containing 0%,10%,20% and 85% of ethanol in volume respectively were prepared to investigate the effects of ethanol/gasoline blends(gasohol) on engine unregulated emissions.A multiple-point injection gasoline engine was applied in the experiment and the unregulated emissions were detected by a gas chromatography with a pulsed discharge helium ionization detector.The performance of a three-way catalytic converter(TWC) was examined.The experimental results show that the emissions of formaldehyde,acetaldehyde and ethanol increased with the increase of ethanol ratio in E10 and E20.The emission of formaldehyde and acetaldehyde from the engine with E85 increased slightly,about 1.6 and 2.4 times as large as that with E0,respectively,while the emission of ethanol was about 35 times as large as that with E10.The emission of acetaldehyde increased with the load,and the ethanol emission from the engine with E10 or E20 decreased but that with E85 increased slightly with the increase in the load.The conversion efficiency of aldehyde and ethanol emissions with TWC was above 75% while the conversion efficiency of formaldehyde emission from the engine with E20 or E85 was less than 30%.
出处 《西安交通大学学报》 EI CAS CSCD 北大核心 2010年第1期13-16,116,共5页 Journal of Xi'an Jiaotong University
基金 国家自然科学基金资助项目(50876088)
关键词 乙醇汽油 非常规排放 气相色谱仪 三效催化器 gasohol unregulated emissions gas chromatography three-way catalytic converter
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参考文献8

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