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空气环境下制备相变特性VO_2薄膜

The Fabrication of Phase Transition Characteristic VO_2 Thin Films in Air Atmosphere
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摘要 提出了一种制备相变特性VO2薄膜的简易方法.将制备好的金属钒薄膜置于440℃空气下氧化处理,获得相变温度为60℃的单斜VO2薄膜,薄膜方块电阻值在60~85℃范围内变化量达2.2个数量级.X射线衍射分析(XRD)表明薄膜的主要成分为单斜相VO2.探索了此工艺的一般性规律,分析高价态钒对薄膜相变的影响. A simple method on the fabrication of phase transition characteristic VO2 thin films was presented. Monoclinic VO2 film which phase change at 60 ℃was obtained by treating V-metal films in air atmosphere at 440℃. The prepared samples exhibited an 2.2 order change on square resistance from 60℃ to 85 ℃. X-ray diffraction (XRD) showed the chief constituent in film was polycrystalline monoclinic phase VO2. The universal rule of the technique was studied and the influence of the high-valence V to the phase transition characteristic in the films were also discussed.
作者 刘洋 徐晓峰
机构地区 东华大学理学院
出处 《东华大学学报(自然科学版)》 CAS CSCD 北大核心 2009年第6期743-746,共4页 Journal of Donghua University(Natural Science)
关键词 VO2薄膜 相变 空气环境 氧化 方块电阻 VO2 thin films phase transition air atmosphere oxidation square resistance
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